ORGANIC CARBON ISOTOPE PERTURBATIONS IN THE CRETACEOUSPALEOGENE ORGANIC-RICH SEQUENCE, CENTRAL EGYPT

M. El-Shafeiy
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Abstract

The Cretaceous-Paleogeneorganic-rich sediments of central Egypt are preserved as laterally extensive organic-rich successions that are represented mainly by the Duwi and Dakhla formations. Numerous studies were concerned their hydrocarbon source rock potential, trace metal accumulation, and molecular fossils composition. Very rare studies were concerning their organic carbon isotopic composition. The present study; however, investigates the 13C of bulk organic matter as well as the δC of primary productivity tracers (pristane and phytane) for samples from two drilled cores in the Quseir and Abu Tartur areas. The results of the CTOC values indicate that the organic carbon, is essentially derived from a mixture of C3 land-plants and marine plankton. The short-term variability in the δCTOC and δCTOC of the pristane and phytane across the Duwi Formation is mostly related to paleoecological factors and photosynthesis. The uppermost Duwi/lowermost Dakhla strata, which represent a maximum flooding surface, show a negative δCTOC of magnitude -1 to -2‰ and -4 to -6‰ in the bulk organic carbon and bioproductivity tracers, respectively. Such perturbation can be most probably related to density stratification and overturn, although more investigations are required for the different hypotheses.
埃及中部白垩纪-古近纪富有机质层序中的有机碳同位素扰动
埃及中部白垩系—古近系富有机质沉积被保存为横向广泛的富有机质序列,主要以Duwi和Dakhla组为代表。对其烃源岩潜力、微量金属富集、分子化石组成等进行了大量研究。对其有机碳同位素组成的研究很少。本研究;然而,在Quseir和Abu Tartur地区的两个钻孔岩心中,研究了大块有机质的13C以及初级生产力示踪剂(原生岩和植烷)的δC。CTOC值的结果表明,有机碳主要来自C3陆地植物和海洋浮游生物的混合物。杜威组原石和植烷的δCTOC和δCTOC的短期变化主要与古生态因素和光合作用有关。最上层Duwi/最下层Dakhla地层为最大泛洪面,整体有机碳和生物生产力示踪剂δCTOC值分别为-1 ~ -2‰和-4 ~ -6‰。这种扰动很可能与密度分层和倾覆有关,尽管需要对不同的假设进行更多的研究。
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