Effect of Wettability Alteration in Chemical Enhanced Imbibition Using Surfactants with Different IFT Magnitudes for Carbonates

Z. Qi, H. Ming, J. Wang, A. Alsofi
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Abstract

Introduction A large amount of carbonate reservoirs are characterized as preferentially oil-wet or intermediate wet (Okasha et al., 2007). In such reservoirs, the spontaneous imbibition of injection fluid into the carbonate matrix represents an important recovery mechanism. The enhancement of imbibition can be achieved by reduction of interfacial tension between oil and water phases, and wettability alteration of rock surface. Among the two factors, wettability alteration is considered dominating when conducting spontaneous imbibition, and many imbibition experiments have been reported in the literature targeting the wettability alteration to enhance oil production using different methods (Al-Hadhrami and Blunt, 2001; Zhang et al., 2006). Optimizing the salinity and ionic composition of injection brine can alter the wettability of carbonate rock surface because of surface charge alteration and microscopic anhydrite dissolution (RezaeiDoust et al., 2009). It was also reported that the favorable low salinity SmartWater/polymer synergy extends to spontaneous imbibition (AlSofi et al., 2019). The trials of optimized brine injection confirmed that in-house research results can be replicated at the well level (Yosef et al., 2012). Nanoparticles have been studied extensively for their wettability alteration ability. The presence of nanoparticles in the three-phase contact region creates a wedge structure, resulting in the removal of oil from the surface (Nazari et al., 2015).
不同IFT量级表面活性剂对碳酸盐化学增强渗吸润湿性的影响
大量碳酸盐岩储层的特征为优先亲油或中湿性(Okasha et al., 2007)。在此类储层中,注入流体在碳酸盐基质中的自吸作用是一种重要的采收率机制。通过降低油水界面张力和改变岩石表面润湿性来增强渗吸。在这两个因素中,润湿性改变被认为是自发渗吸的主导因素,文献中已经报道了许多针对润湿性改变的渗吸实验,使用不同的方法来提高石油产量(Al-Hadhrami和Blunt, 2001;Zhang等人,2006)。由于表面电荷改变和微观硬石膏溶解,优化注入盐水的盐度和离子组成可以改变碳酸盐岩表面的润湿性(RezaeiDoust et al., 2009)。据报道,有利的低盐度SmartWater/聚合物协同作用扩展到自发渗吸(AlSofi等,2019)。优化的盐水注入试验证实,内部研究结果可以在井级上复制(Yosef et al., 2012)。纳米颗粒因其润湿性和改变能力而受到广泛的研究。纳米颗粒在三相接触区域的存在产生了一个楔形结构,导致油从表面去除(Nazari et al., 2015)。
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