NANOMATERIALS IN TREATMENT AND CONSERVATION OF ARCHAEOLOGICAL BUILDINGS FAÇADES IN HISTORIC CAIRO AFFECTED BY AIR POLLUTION

M. Kamal
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Abstract

Islamic Cairo is a part of central Cairo noted for its historically important mosques and other Islamic monuments. Islamic Cairo was founded in (969 AD) as the royal enclosure for the Fatimid caliphs. Cairo contains the greatest concentration of Islamic monuments in the world, and its mosques, mausoleums, religious schools and baths were built between the seventh and nineteenth centuries. The air pollution in Cairo is a matter of serious concern. Archaeological buildings in Cairo suffer from different deterioration phenomena for example, black crust formation, chemical alterations, disintegration between surface mineral grains, pitting, cracks, missing parts, erosion, and white stains. Building materials which include limestone and marble in addition to salts and surface black crusts had been studied by polarizing microscope (PM), scanning electron microscope (SEM) and X-ray diffraction (XRD) to identify their components and their deterioration. Study for the effect of nano titanium dioxide and nano lime on stone samples was carried out. Results of stone samples treatment with nanomaterials were evaluated. Nano titanium dioxide gave a good effect in self-cleaning and nanolime (CaLoSiL IP25) gave the best result in consolidation of limestone and marble samples.
纳米材料在处理和保护考古建筑faÇades受空气污染影响的历史开罗
伊斯兰开罗是开罗市中心的一部分,以其历史上重要的清真寺和其他伊斯兰纪念碑而闻名。伊斯兰开罗始建于公元969年,是法蒂玛王朝哈里发的皇家领地。开罗拥有世界上最集中的伊斯兰纪念碑,清真寺、陵墓、宗教学校和浴室建于7世纪到19世纪之间。开罗的空气污染是一个令人严重关切的问题。开罗的考古建筑遭受不同的退化现象,例如黑色外壳的形成、化学变化、表面矿物颗粒之间的解体、点蚀、裂缝、部分缺失、侵蚀和白色污渍。利用偏光显微镜(PM)、扫描电镜(SEM)和x射线衍射仪(XRD)对石灰石、大理石等建筑材料及其表面的盐和黑色结块进行了研究,以确定其成分及其变质情况。研究了纳米二氧化钛和纳米石灰对石材试样的影响。评价了纳米材料对石材样品的处理效果。纳米二氧化钛具有良好的自清洁效果,纳米石灰(CaLoSiL IP25)对石灰石和大理石样品的固结效果最好。
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