The Chemical Modification of Calophyllum Inophyllum Plant Oil for Potential Base Oil in Drilling Mud Operation

C. Onuh, Dosunmu Adewale, Anawe A. L. Paul, Rotimi Oluwatosin
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引用次数: 1

Abstract

Research on the use of plant oil or ester oil in drilling mud operation is on the increase. The is due to the less toxic and low cost advantage over the commercial synthetic base oil. Despite the attractive physicochemical properties of vegetable oil samples, it deteriorates and becomes unstable under downhole temperature and aging conditions when used directly in mud formulation. Hence, plant oil needs improvement in order to be compared to the conventional base oil. Calophyllum inophyllum oil was extracted and reacted with methano in the presence of catalyst to form biodiesel. The physicochemical properties of the commercial synthetic base oil, extracted Calophyllum inophyllum oil, and biodiesel Calophyllum inophyllum oil were measured and compared to the EN14214 and the ASTM D6751 standards. The commercial synthetic oil, Calophyllum inophyllum oil, and biodiesel Calophyllum inophyllum oil had a flash point of 101 ± 0.1, 164 ± 0.1, and 146 ± 0.1 °C respectively; density of 108, 172, and 152 (kgm3) respectively; viscosity index of 192, 163, and 282 respectively; acid value of 0.953, 24.24, and 1.0 respectively, and oil yield of NA, 71, and 62 respectively. The result showed that the biodiesel can also serve as alternative to commercial synthetic base oil due to their comparable property to the commercial base oil. The biodiesel Calophullum inophyllum oil is a potential base oil for drilling mud formulation.
石竹油的化学改性作为钻井泥浆作业中潜在基础油
在钻井泥浆作业中使用植物油或酯油的研究日益增多。与商业合成基础油相比,其毒性更小,成本更低。尽管植物油样品具有吸引人的物理化学性质,但当直接用于泥浆配方时,它会在井下温度和老化条件下变质,变得不稳定。因此,与传统的基础油相比,植物油需要改进。以茶树油为原料,在催化剂作用下与甲醇反应制备生物柴油。测量了商业合成基础油、提取的茶树油和生物柴油茶树油的物理化学性质,并与EN14214和ASTM D6751标准进行了比较。商品合成油、茶树油和生物柴油的闪点分别为101±0.1、164±0.1和146±0.1°C;密度分别为108、172、152 (kgm3);粘度指数分别为192、163、282;酸值分别为0.953、24.24、1.0,出油率分别为71、62。结果表明,生物柴油与工业合成基础油性能相当,可作为工业合成基础油的替代品。该生物柴油油是一种潜在的钻井泥浆配方基础油。
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