Per- and Trichloroethylene Air Monitoring in Dry Cleaners in the City of Sfax (Tunisia)

F. Omrane, I. Gargouri, M. Khadhraoui
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Abstract

The use of chlorinated solvents in dry cleaning poses risks to human health. The occupational health exposure assessment to these volatile chemicals is conducted through quantification of airborne concentrations inside the facilities. Indeed, the lack of such measurements in Tunisia pushed us to conduct the study. After identifying dry cleaners in Sfax city, we conducted door-to-door canvassing in 47 facilities. Then, the levels of perchloroethylene (PCE) and trichloroethylene (TCE) in the indoor air are measured in two sampling positions: fixed and individual. The pollutants are adsorbed with charcoal sorbent tubes where their amounts correspond to given air volumes that are suctioned through the pump. It is later used to calculate their mean concentrations. These solvents are desorbed using carbon disulfide and analyzed by gas chromatography—flame ionization detection. After the analytical validation of the protocol, 19 air samples were quantified. The measured concentrations of TCE are close to the occupational exposure limit value in almost all facilities, whereas the PCE concentrations are about half of the OELV. The overall results showed that the working environment in dry cleaning in Sfax city are concerning and can lead to many adverse health effects up to several types of cancers.
斯法克斯市(突尼斯)干洗店中二氯乙烯和三氯乙烯空气监测
在干洗中使用氯化溶剂对人体健康构成威胁。对这些挥发性化学品的职业健康暴露评估是通过对设施内空气中的浓度进行量化来进行的。事实上,突尼斯缺乏这样的测量促使我们进行这项研究。在确定了斯法克斯市的干洗店后,我们在47个设施进行了挨家挨户的拉票。然后,在固定和单独两个采样位置测量室内空气中过氯乙烯(PCE)和三氯乙烯(TCE)的水平。污染物被木炭吸附管吸附,其中它们的量对应于通过泵吸入的给定空气量。然后用它来计算它们的平均浓度。这些溶剂用二硫化碳解吸,用气相色谱-火焰电离检测法分析。在对方案进行分析验证后,对19个空气样本进行了定量分析。在几乎所有设施中,测量到的TCE浓度接近职业暴露极限值,而PCE浓度约为OELV的一半。总体结果表明,斯法克斯市干洗店的工作环境令人担忧,并可能导致许多不利的健康影响,包括几种癌症。
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