The effect of NiMo catalysts preparation method on the hydrodeoxygenation of sunflower oil

A. Nepomnyashchiy, E. A. Buluchevskiy, A. Lavrenov
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Abstract

The possibility of obtaining diesel fuel components by refining sunflower oil on nickel-molybdenum catalysts, with varying synthetic methods and preliminary preparation conditions were considered. Ni and Mo based bimetallic catalysts prepared from mono- and bi-metallic precursors in sulfide form provide a hydrocarbons yield of 74.6-82.5 % containing predominantly fractions of n-alkanes (88-95%). The period of stable operation of the systems is at least 500 hours.The possibility of obtaining diesel fuel components by refining sunflower oil on nickel-molybdenum catalysts, with varying synthetic methods and preliminary preparation conditions were considered. Ni and Mo based bimetallic catalysts prepared from mono- and bi-metallic precursors in sulfide form provide a hydrocarbons yield of 74.6-82.5 % containing predominantly fractions of n-alkanes (88-95%). The period of stable operation of the systems is at least 500 hours.
NiMo催化剂制备方法对葵花籽油加氢脱氧的影响
研究了在镍钼催化剂上精制葵花籽油制备柴油组分的可能性,以及不同的合成方法和初步制备条件。由硫化物形式的单金属和双金属前体制备的Ni和Mo基双金属催化剂的碳氢化合物产率为74.6- 82.5%,主要含有正构烷烃(88-95%)。系统稳定运行时间不少于500小时。研究了在镍钼催化剂上精制葵花籽油制备柴油组分的可能性,以及不同的合成方法和初步制备条件。由硫化物形式的单金属和双金属前体制备的Ni和Mo基双金属催化剂的碳氢化合物产率为74.6- 82.5%,主要含有正构烷烃(88-95%)。系统稳定运行时间不少于500小时。
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