Study of nickel precursors in (Ni,M,Ti)O2 (M = Sb, Nb) yellow ceramic pigments

S. Šorli, M. A. Tena, J. Badenes, M. Llusar, G. Monrós
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引用次数: 7

Abstract

Abstract NixTi1 - 3xM2xO2 (M = Sb, Nb; 0·05 ≤ x ≤ 0·10) samples have been synthesised from mixtures of NiO, Nb2O5, Sb2O3, and TiO2. From characterisation of these samples, x = 0·05 was chosen to compare results with different nickel precursors. Thus samples of Ni0·05Ti0·85M0·10O2 (M = Sb, Nb) were also prepared from NiCO3.3Ni(OH)2.4H2O, NiCl2.6H2O, Ni(NO3)2.6H2O, NiSO4.6H2O, and Ni(CH3COO)2.4H2O. A eutectic mixture of alkaline halides (NaF:2NaCl) was used as fluxing agent. Optimal yellow colour was found in the mixture of NiSO4.6H2O, Sb2O5, and TiO2 fired at 1100°C for 2 h.
(Ni,M,Ti)O2 (M = Sb, Nb)黄色陶瓷颜料中镍前驱体的研究
NixTi1 - 3xM2xO2 (M = Sb, Nb;用NiO、Nb2O5、Sb2O3和TiO2的混合物合成了0.05≤x≤0.10的样品。从这些样品的表征中,选择x = 0·05来比较不同镍前驱体的结果。以NiCO3.3Ni(OH)2.4H2O、NiCl2.6H2O、Ni(NO3)2.6H2O、NiSO4.6H2O、Ni(CH3COO)2.4H2O为原料制备了Ni0·05Ti0·85M0·10O2 (M = Sb, Nb)样品。采用碱性卤化物共晶混合物(NaF:2NaCl)作为助熔剂。在NiSO4.6H2O, Sb2O5和TiO2的混合物中,在1100℃下焙烧2 h,发现最佳的黄色。
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