Photocatalytic properties of N-doped TiO2. the effect of the synthesis procedure

C. Pastravanu, I. Alexa, I. Cretescu, E. Popovici
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Abstract

TiO2 is the most frequently employed photocatalyst in realising complete mineralization of organic pollutants in water treatment. Its large bandgap energy necessitates though UV excitation to induce charge separation within the particle. Nitrogen doped into substitutional sites of TiO2 has shown bandgap narrowing and photocatalytic activity in the visible light. N-doped and non-doped mesoporous titania were synthesized using hydrothermal and ultrasound methods. Titanium-tetraisopropoxide was used as Ti precursor. UV-VIS and N2 adsorbtion-desorbtion techniques were used to investigate the structure, morphology and optical properties of these photocatalysts. The photocatalytic activity of mesoporous titania was studied by different dyes photoreactions.
n掺杂TiO2的光催化性能。合成过程的效果
在水处理中,TiO2是实现有机污染物完全矿化最常用的光催化剂。它的大带隙能量需要通过紫外激发来诱导粒子内的电荷分离。在TiO2的取代位上掺杂氮,在可见光下表现出带隙缩小和光催化活性。采用水热法和超声法合成了n掺杂和非掺杂介孔二氧化钛。采用钛-四异丙醇作为钛前驱体。采用UV-VIS和N2吸附-解吸技术对这些光催化剂的结构、形貌和光学性能进行了研究。通过不同染料的光催化反应,研究了介孔二氧化钛的光催化活性。
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