Phase Transitions and Structure of Liquid Crystalline Cellulose Ether Solutions in a Magnetic Field and in Its Absence

S. Vshivkov, E. Rusinova
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Abstract

The results of research studies of a magnetic field effect on structure and phase transitions of liquid crystalline polymer systems are described. Influence of intensity of the magnetic field, molecular weight, and concentration of polymers in solutions on the phase diagrams is analyzed. The dependences of boundary curves on the chemical structure of polymers and solvents are discussed. Results of theoretical researches of the magnetic field effect on the diamagnetic macromolecule orientation in solutions are described. The shift of boundary curves of liquid crystalline cellulose derivative systems is compared with the energy of magnetic field stored by solutions.
液晶纤维素醚溶液在磁场和无磁场条件下的相变和结构
介绍了磁场对液晶聚合物体系结构和相变影响的研究结果。分析了磁场强度、溶液中聚合物的分子量和浓度对相图的影响。讨论了边界曲线与聚合物和溶剂化学结构的关系。介绍了磁场对溶液中抗磁性大分子取向影响的理论研究结果。将液晶纤维素衍生物体系的边界曲线位移与溶液储存的磁场能量进行了比较。
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