Synthesis and Characterization of Activated Carbon Prepared from Jute Stick Charcoal for Industrial Uses

M. N. Islam, J. Sarker, A. Khatton, S. Hossain, H. A. Sikder, R. Ahmed, A. Chowdhury
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Abstract

Activated Carbons (ACs) were prepared from jute stick charcoal by chemical activation using H2SO4 and H3PO4 ranging temperature from 3000C to 3500. The activated carbons and charcoal prepared from jute sticks were characterized by evaluating the surface chemistry, structural features and surface morphology. The properties of the carbons were characterized by Scanning Electron Microscope (SEM), Brunauer – Emmett-Teller (BET), X-Ray Diffraction (XRD) and the FT-IR method. The jute sticks were converted to activated carbons with the highest surface area (135–245m2/g) and largest mesopores volume (0.14–0.16 cm3/g). The FT-IR spectra exhibited that the pyrolysis of jute stick resulted in the release of aliphatic and O - containing functional groups by thermal effect. However, the release of functional groups is effect of chemical reaction in the ZnCl2, H3PO4, and H2SO4 activation process. A honeycomb carbon structure in activated carbon was formed as observed on SEM images. Although charcoal and activated carbon were prepared at 3000C to 3500, the activated carbon exhibited much lower Raman sensitivity due to the formation of condensed aromatic ring systems. Due to high surface area and high porous structure with abundance of functional groups, the activated carbon prepared from jute sticks charcoal absorbed molecules with much higher than those of other activated carbon.
工业用黄麻炭制备活性炭的合成与表征
以黄麻炭为原料,在3000 ~ 3500℃的温度下,用H2SO4和H3PO4进行化学活化,制备了活性炭。以黄麻为原料制备活性炭和活性炭,对其表面化学、结构特征和表面形貌进行了表征。采用扫描电镜(SEM)、布鲁诺尔-埃米特-泰勒(BET)、x射线衍射(XRD)和傅里叶变换红外光谱(FT-IR)对碳的性质进行了表征。得到的活性炭比表面积最高(135 ~ 245m2/g),介孔体积最大(0.14 ~ 0.16 cm3/g)。红外光谱分析表明,黄麻热解过程中由于热效应导致脂肪族官能团和含氧官能团释放。而官能团的释放是在ZnCl2、H3PO4和H2SO4活化过程中化学反应的结果。扫描电镜(SEM)观察到活性炭中形成了蜂窝碳结构。虽然活性炭和活性炭在3000 ~ 3500℃的温度下制备,但活性炭由于形成了缩合芳环体系而表现出较低的拉曼灵敏度。黄麻炭制备的活性炭具有比表面积大、多孔结构高、官能团丰富等特点,吸附分子量远高于其他活性炭。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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