Synthesis and toxicity test of tin(IV) pyridine-2,6-dicarboxylate complexes

Imanuel Gauru, F. Martak
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引用次数: 0

Abstract

Binuclear tin(IV) complex with pyridine-2,6-dicarboxylic ligand has been synthesized using reflux method. The colorless crystals with cubic shape were obtained. Elemental analysis of Tin(IV) Pyridine-2,6-Dicarboxylate Complexes clearly indicates that the contents of carbon, hydrogen, and nitrogen in the complex were 31,74%, 3.08%, 4.23% by weight. The measurement of tin levels in the complexes by Atomic Absorption Spectroscopy (AAS) shows the results of 34.80% by weight. The IR spectrum showed absorption peaks of Sn-N and Sn=O at 432.05 and 732.95 cm−1 respectively, confirming the formation of complex. Toxicity of the complex was determined by Brine Shrimp Lethality Test (BSLT) method, and the LC50 value of the complex was 23.81 mg/L.
锡(IV)吡啶-2,6-二羧酸配合物的合成及毒性试验
用回流法合成了吡啶-2,6-二羧基双核锡配合物。得到了立方形状的无色晶体。锡(IV)吡啶-2,6-二羧酸配合物的元素分析表明,配合物中碳、氢、氮的含量分别为31、74%、3.08%、4.23%(重量计)。用原子吸收光谱法(AAS)测定配合物中锡的含量,结果为34.80%(重量计)。红外光谱显示Sn- n和Sn=O的吸收峰分别在432.05和732.95 cm−1处,证实了配合物的形成。采用卤虾致死试验(BSLT)法测定配合物的毒性,其LC50值为23.81 mg/L。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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