RESEARCH OF THE MECHANISM OF FIRE PROTECTION OF FABRICS WITH INTUMESCENT COATINGS

Y. Tsapko, O. Bondarenko, А. Tsapko, Yuriy Sarapin, D. Zherebchuk
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Abstract

Describing the behavior of fire retardants and coatings, including swelling, at the time of formation of the insulating structure is a separate and complex task. In general, it covers both stages of the heat protection process: as a rule, the decomposition of flame retardants under the action of temperature with heat absorption and the release of non-combustible gases, and then - swelling of the coating formed by fire protection. Therefore, it is necessary to study the conditions for the formation of a barrier to thermal conductivity and the establishment of a fire protection mechanism from layer to layer of coke. In this regard, a study of the process of fire protection during the operation of the fire protection coating. According to the data obtained, it is found that the formation of volatile products under the action of high temperature on the coating takes place with the formation of non-combustible substances. It has been experimentally established that under the action of heat flow on fire-retardant samples there is an intensive release of inert gases and a reduction of combustibles in reverse order. This proves the effectiveness of fire protection. During the tests it was found that the intensity of the formation of the swollen layer of coke moves in the direction of elevated temperature. The results of determining the swelling capacity of the coating for the intumescent system showed that under the action of high-temperature flow the burnout of the material and the loss of coating weight are reduced more than twice due to the formation of high-temperature compounds. The coating under the action of high temperature forms a significant coefficient of swelling, promotes the formation of a heat-insulating layer of coke, preventing burnout of the fabric and the passage of high temperature to the material, which is confirmed by reduced heat of combustion. It was determined that the fire-retardant fabric has almost 1.3 times less heat of combustion and is characterized by thermal decomposition by reducing flammable gases by more than 50% and increasing inert gases by more than 8 times.
膨胀涂层织物防火机理的研究
描述阻燃剂和涂料在绝缘结构形成时的行为,包括膨胀,是一项单独而复杂的任务。一般来说,它涵盖了热防护过程的两个阶段:通常,阻燃剂在温度作用下分解,吸收热量并释放不燃气体,然后对防火形成的涂层进行膨胀。因此,有必要研究从一层到另一层的焦炭形成导热屏障和建立防火机制的条件。对此,研究了防火涂料在防火操作过程中的作用。根据所获得的数据,发现在高温作用下涂层挥发性产物的形成是伴随着不可燃物质的形成而发生的。实验证实,在热流作用下,惰性气体大量释放,可燃物按相反顺序减少。这证明了消防的有效性。在试验过程中发现,焦炭膨胀层的形成强度随温度升高的方向变化。测定膨胀体系涂层的膨胀能力的结果表明,在高温流动的作用下,由于高温化合物的形成,材料的燃尽和涂层重量的损失减少了两倍以上。涂层在高温作用下形成显著的膨胀系数,促进了焦炭隔热层的形成,防止了织物的燃尽和高温向物料的传递,燃烧热的降低证实了这一点。测定该阻燃织物的燃烧热几乎降低了1.3倍,其特点是可燃气体减少50%以上,惰性气体增加8倍以上,从而实现热分解。
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