Study of the corrosion inhibition of C38 steel in a 1M HCl medium by the etanoic extract of Rumex Nervosus Vahl leaves

Abstract

The efficacy of Rumex Nervosus Vahl Leaves Ethanolic extract (RNVLE) to inhibit C38 steel corrosion in one molar hydrochloric acid medium was examined using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. Polarization measurements revealed mixed-type inhibitor behavior. The inhibitory efficacy assessed by both polarization and (EIS) techniques was consistent, with an IE value of (96.0 %) and (95.5 %) at 2g/L of RNVLE, respectively. The RNVLE adsorption on the C38 metal surfaces in 1M HCl follows the Langmuir adsorption isotherm. The calculated free energy (G°ads equal to -16.1 KJ mol-1) explained that RNVLE controls the corrosion process by physisorption. The effect of immersion time was also investigated. This study demonstrated that RNVLE can be considered an excellent inhibitor up to 6 hours and after this time; it is considered a lower quality inhibitor although it still has sufficient inhibitory ability. SEM-EDX (Scanning Electron Microscopy and X-ray Energy Dispersive Spectroscopy) analysis revealed that the extract molecules adsorb on the metal's surface. These findings indicate that RNVLE can be used as an effective corrosion inhibitor for C38 steel in 1M HCl solution.