Elution and Mechanical Characteristics of Municipal Solid Waste (MSW) Incineration Bottom Ash that has Undergone Accelerated Carbonation Treatment using CO2 Recovered from Incineration Plant Exhaust

Koga Shigeizumi, H. Kubota, Haruna Kochi, Kenichi Sato, T. Fujikawa, Yosuke Nagayama, H. Sakanakura, Daigo Fujita
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Abstract

Accelerated carbonation treatment for recycling MSW incineration bottom ash can simultaneously reduce CO 2 emissions. In this study, we designed a public implementation of this technology and conducted a test at the Saga City Incineration Plant, which has CO 2 separation and capture facilities. Two types of gas-exhaust gas from the same incineration plant and CO 2 separated and recovered from such exhaust gas-were ventilated through the bottom ash and used to investigate the elution characteristics of heavy metals (through (1) elution testing and (2) lysimeter testing) and the effects of carbonation treatment on their mechanical characteristics as civil engineering materials. Carbonation significantly reduced the Pb elution concentration in both (1) and (2), but the concentrations of Cr(VI) increased in both (1) and (2). There was no difference for B between untreated and treated bottom ash in (1), but in (2) the concentration was lower than that of untreated. Regarding mechanical characteristics, we confirmed that while carbonation reduced the modified CBR value and cone index, strength was satisfied as a material for roadbeds and embankments. For the gas types, there were differences in the carbonation reaction status and B concentration behavior.
利用焚烧厂废气中回收的CO2进行加速碳化处理的城市生活垃圾焚烧底灰的洗脱和力学特性
加速碳化处理回收城市生活垃圾焚烧底灰,可同时减少co2的排放。在这项研究中,我们设计了一项公共实施这项技术,并在Saga市焚烧厂进行了测试,该焚烧厂拥有二氧化碳分离和捕获设施。将同一焚烧厂的两种气体废气和从废气中分离回收的CO 2通过底灰通风,研究重金属的洗脱特性(通过(1)洗脱试验和(2)渗滤试验)以及碳化处理对其作为土木工程材料的力学特性的影响。碳化处理显著降低了(1)和(2)中Pb的浓度,但(1)和(2)中Cr(VI)的浓度均升高。(1)中未处理和处理的底灰中B的浓度没有差异,但(2)中B的浓度低于未处理的浓度。在力学特性方面,我们证实碳化降低了改性CBR值和锥指数,但强度满足路基和路堤材料的要求。不同气体类型在碳酸化反应状态和B浓度行为上存在差异。
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