Development of nanofibers composite Polyaniine/CNT fabricated by Electro spinning Technique for CO Gas Sensor

Y. Wanna, S. Pratontep, A. Wisitsoraat, A. Tuantranont
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引用次数: 6

Abstract

Conducting Polyaniline (PANI) doped Maleic acid (MA) blending with Polyvinyl alcohol (PVA) and Carbon nanotube (CNT) nanofiber has been fabricated by electrospun technique. Structural and morphological characterization has been carried out by means of SEM, XRD and TEM in order to correlate structural properties with gas sensing behavior. The sensors were tested for CO sensing at room temperature with CO concentrations in the range of 100-500 ppm. In comparisons to PANI prepared by solvent casting technique with no CNT inclusion, the sensitivity of the nanofiber composite was increased by more than two orders of magnitude and response/recovery times were reduced by more than the factor of 3. The results, therefore, suggest that the electro spun PANI/PVA composite of CNT in MA-doped. PANI is a promising method for achieving a conductive polymer gas sensor with good sensitivity, fast response, low-concentration detection and room-operating-temperature capability.
电纺丝技术制备聚苯胺/碳纳米管复合纳米纤维用于一氧化碳气体传感器的研制
采用静电纺丝技术制备了导电聚苯胺(PANI)掺杂马来酸(MA)与聚乙烯醇(PVA)和碳纳米管(CNT)纳米纤维共混的材料。通过SEM、XRD和TEM等手段对其进行了结构和形态表征,以确定其结构性能与气敏行为之间的关系。在100- 500ppm的CO浓度范围内,测试了传感器在室温下的CO传感性能。与未掺杂碳纳米管的溶剂铸造法制备的聚苯胺相比,纳米纤维复合材料的灵敏度提高了两个数量级以上,响应/恢复时间降低了3倍以上。因此,结果表明,电纺PANI/PVA复合材料的碳纳米管在ma掺杂。聚苯胺是一种具有良好灵敏度、快速响应、低浓度检测和室温工作能力的导电聚合物气体传感器。
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