MOCVD Epitaxy of α-(AlxGa1−x)2O3 (x =0–100%) on m-Plane Sapphire Substrate

A. Bhuiyan, Zixuan Feng, Hsien-Lien Huang, Lingyu Meng, Jinwoo Hwang, Hongping Zhao
{"title":"MOCVD Epitaxy of α-(AlxGa1−x)2O3 (x =0–100%) on m-Plane Sapphire Substrate","authors":"A. Bhuiyan, Zixuan Feng, Hsien-Lien Huang, Lingyu Meng, Jinwoo Hwang, Hongping Zhao","doi":"10.1109/csw55288.2022.9930429","DOIUrl":null,"url":null,"abstract":"Phase pure single crystal α-(Al<inf>x</inf>Ga<inf>1−x</inf>)<inf>2</inf>O<inf>3</inf> thin films are successfully grown on m-plane sapphire substrate via MOCVD. Comprehensive characterization by XRD, RSM mapping, atomic resolution STEM, Raman spectroscopy, SEM, AFM and XPS measurements reveal high quality epitaxial growth of α-(Al<inf>x</inf>Ga<inf>1−x</inf>)<inf>2</inf>O<inf>3</inf> thin films over the entire Al composition range (x=0–100%) and α-GaO/AlGaO superlattice structures with smooth surface morphology, sharp interfaces, and homogenous Al distribution. The bandgap energies of 5.41 eV (x=0) to 8.81 eV (x=1) are extracted from XPS measurements. The determined band offsets reveal a type-I band alignment at the α-AlGaO/GaOinterfaces with valance and conduction band offsets of 0.27 eV and 3.13 eV between α-Ga<inf>2</inf>O<inf>3</inf> and α-Al<inf>2</inf>O<inf>3</inf>, respectively.","PeriodicalId":382443,"journal":{"name":"2022 Compound Semiconductor Week (CSW)","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"2022 Compound Semiconductor Week (CSW)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/csw55288.2022.9930429","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

Phase pure single crystal α-(AlxGa1−x)2O3 thin films are successfully grown on m-plane sapphire substrate via MOCVD. Comprehensive characterization by XRD, RSM mapping, atomic resolution STEM, Raman spectroscopy, SEM, AFM and XPS measurements reveal high quality epitaxial growth of α-(AlxGa1−x)2O3 thin films over the entire Al composition range (x=0–100%) and α-GaO/AlGaO superlattice structures with smooth surface morphology, sharp interfaces, and homogenous Al distribution. The bandgap energies of 5.41 eV (x=0) to 8.81 eV (x=1) are extracted from XPS measurements. The determined band offsets reveal a type-I band alignment at the α-AlGaO/GaOinterfaces with valance and conduction band offsets of 0.27 eV and 3.13 eV between α-Ga2O3 and α-Al2O3, respectively.
m平面蓝宝石衬底上α-(AlxGa1−x)2O3 (x = 0-100%)的MOCVD外延
采用MOCVD技术在m平面蓝宝石衬底上成功生长出相纯单晶α-(AlxGa1−x)2O3薄膜。通过XRD, RSM作图,原子分辨率STEM,拉曼光谱,SEM, AFM和XPS测量等综合表征表明,α-(AlxGa1−x)2O3薄膜在整个Al成分范围(x= 0-100%)内具有高质量的外延生长,α- gao /AlGaO超晶格结构具有光滑的表面形貌,尖锐的界面和均匀的Al分布。从XPS测量中提取了5.41 eV (x=0) ~ 8.81 eV (x=1)的带隙能量。α-Ga2O3和α-Al2O3之间的价带和导带偏移量分别为0.27 eV和3.13 eV, α-Al2O3与α-Al2O3界面处的能带偏移量为i型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
自引率
0.00%
发文量
0
文献相关原料
公司名称 产品信息 采购帮参考价格
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信