Electroluminescence Characteristics of Epoxy/TiO2 Nanocomposites

M. Hirai, M. Kurimoto, K. Tohyama, T. Sawada, S. Yoshida, T. Umemoto, H. Muto
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Abstract

The AC breakdown strength of epoxy/TiO2 nanocomposites (NC) with agglomerate sizes smaller than 50 nm is higher than that of unfilled epoxy. However, the mechanism responsible for this breakdown strength enhancement has not been clarified. Observing the electroluminescence (EL) of these materials may provide insight into insulation deterioration in the early stages. This study investigated the EL characteristics of unfilled epoxy and NC to clarify the mechanism for the enhancement of the breakdown strength. We fabricated NCs with controlled agglomerate sizes using centrifugation. The EL of NC was measured under an AC ramp electric field. The number of EL pulses of the NC is found to be less than that of the unfilled epoxy. The EL inception and extinction electric fields of the NC are higher than those of the unfilled epoxy. These results indicate that the dispersed nanoparticles suppress EL generation.
环氧树脂/TiO2纳米复合材料的电致发光特性
团聚粒径小于50 nm的环氧/TiO2纳米复合材料(NC)的交流击穿强度高于未填充的环氧。然而,这种增强击穿强度的机制尚未明确。观察这些材料的电致发光(EL)可以在早期阶段提供对绝缘恶化的见解。本文研究了未填充环氧树脂和NC的电致发光特性,以阐明其提高击穿强度的机理。我们用离心法制备了具有控制团聚体大小的nc。在交流斜坡电场作用下,测量了NC的EL。发现NC的EL脉冲数比未填充的环氧树脂少。NC的EL起始电场和消光电场均高于未填充的环氧树脂。这些结果表明,分散的纳米颗粒抑制了EL的产生。
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