Photocatalytic Degradation of Organic Pollutants: The Case of Conductive Polymer Supported Titanium Dioxide (TiO2) Nanoparticles: A Review

T. B. Mekonnen, A. Mengesha, Hirpo Hinsene Dube
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Abstract

In recent years development of different type of industries are enlarged and these industries are connected with the discarding of organic pollutants which are harmful to aquatic system and the human health. The presence of those organic pollutants in the aquatic system can result in pollution of wastewater which affects the ecosystem. Therefore, the removals of pollutants have become an ecological concern and they are vital for the environmental sustainability. Many practices have been widely applied in the treatment of organic effluent such as biological treatment, reverse osmosis, ozonation, filtration, adsorption on solid phases, incineration, and coagulation. However, each of the methodologies has its own advantages and limitations. The recent research demonstrates that advanced oxidation processes (AOPs) based on photocatalysts are valuable and this method benefits complete mineralization of organic molecules into nontoxic CO2 and H2O at the atmospheric conditions by generating active species such as hydroxyl radicals (•OH) which can remove even non-biodegradable organic compounds from wastewater. These review papers give an overview of the enhanced photocatalytic activities of titanium dioxide (TiO2) based photocatalyst. An effort has also been made to give an overview of expedient photocatalytic activity of these supported nanoparticles for their potential application in environmental remediation. In this review article also, various methods used to enhance the photocatalytic characteristics of TiO2 including doping, coupling and other supporting are discussed. It is observed that the degradation of dyes depends on several parameters like pH, catalyst load, dye concentration, reaction temperature and scavengers on the degradation of dyes.
光催化降解有机污染物:导电聚合物负载二氧化钛纳米颗粒的研究进展
近年来,各类工业的发展规模不断扩大,这些工业都与对水生系统和人体健康有害的有机污染物的排放有关。这些有机污染物在水生系统中的存在会导致废水污染,从而影响生态系统。因此,污染物的清除已成为一个生态问题,对环境的可持续性至关重要。生物处理、反渗透、臭氧氧化、过滤、固相吸附、焚烧、混凝等方法已广泛应用于有机废水的处理。然而,每种方法都有自己的优点和局限性。最近的研究表明,基于光催化剂的高级氧化工艺(AOPs)是有价值的,该方法通过产生羟基自由基(•OH)等活性物质,可以在大气条件下将有机分子完全矿化为无毒的CO2和H2O,甚至可以去除废水中不可生物降解的有机化合物。本文综述了二氧化钛(TiO2)基光催化剂增强光催化活性的研究进展。本文还概述了这些负载纳米颗粒的有利光催化活性及其在环境修复中的潜在应用。本文还讨论了用于增强TiO2光催化性能的各种方法,包括掺杂、偶联和其他支持。观察到染料的降解取决于pH、催化剂负荷、染料浓度、反应温度和清除剂等几个参数对染料降解的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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