Geochemistry of Coal Ash in the Equatorial Wet Disposal System Environment

P. Kolay, Harwant Singh
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Abstract

The coal utilization in thermal power plants in Malaysia has increased significantly which produces an enormous amount of coal combustion by-product (CCBP) or coal ash and poses severe disposal problem. As each coal ash is distinct, this study presents the geochemistry of the coal ash, in particular fly ash, produced from the combustion of local coal from Kuching Sarawak, Malaysia. The geochemical composition of the ash showed a high amount of silica, alumina, iron oxides and alkalies which was found to be a convenient starting material for the hydrothermal synthesis of zeolites with the higher Na2O percentage being a positive factor for its alkaline activation; while the mineral phases are mainly quartz, mullite, calcium oxide, silica, and iron oxide hydrate. The geochemical changes upon alkali activation that can be predicted in a similar type of ash have been described in this paper. The result shows that this particular ash has a good potential for a high value industrial product like zeolites upon alkali activation. Keywords—Coal ash, chemical composition, mineralogical composition, alkali activation, SEM.
赤道湿式处理系统环境下煤灰的地球化学特征
马来西亚火力发电厂的煤炭利用大幅增加,产生了大量的燃煤副产物或煤灰,并造成了严重的处置问题。由于每一种煤灰都是不同的,本研究介绍了来自马来西亚古晋沙捞越当地煤炭燃烧产生的煤灰,特别是飞灰的地球化学。灰分的地球化学组成显示出高含量的二氧化硅、氧化铝、氧化铁和碱,为水热合成沸石提供了方便的起始原料,高Na2O含量是其碱性活化的积极因素;而矿物相主要是石英、莫来石、氧化钙、二氧化硅和氧化铁水合物。本文描述了碱活化后的地球化学变化,可以预测类似类型的灰。结果表明,该灰分经碱活化后具有生产沸石等高价值工业产品的良好潜力。关键词:煤灰,化学成分,矿物成分,碱活化,扫描电镜
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