Recent Advances in High Resolution Fourier Transform Spectroscopy

H. Buijs
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Abstract

Fourier Transform Spectroscopy is now widely used in many routine measurement applications. In principle, very high resolution can be achieved in FT Spectroscopy rivaling the resolution of infrared laser spectroscopy. In practice however, as resolution is increased, a number of operating parameters must be controlled with rapidly increasing care. Refinements of instrumentation over the last few years based on a fuller understanding of these parameters has led not only to excellent realizations of resolution but also to greater precision in observed line shapes, line intensities and frequency calibration. In FT Spectroscopy, higher resolution is achieved by recording the interferogram over increasingly greater mirror displacement or optical path difference. While the optical path difference is increased, it is necessary to maintain a high level of consistency of interferometer alignment, path difference measurement and path difference consistency for all optical rays going through the interferometer.
高分辨率傅立叶变换光谱研究进展
傅里叶变换光谱学现已广泛应用于许多常规测量应用中。原则上,FT光谱可以达到与红外激光光谱相媲美的高分辨率。然而,在实际操作中,随着分辨率的提高,必须更加小心地控制许多操作参数。在过去的几年里,基于对这些参数的更充分的理解,仪器的改进不仅使分辨率得到了很好的实现,而且在观测到的线形、线强度和频率校准方面也有了更高的精度。在傅立叶变换光谱中,通过在越来越大的反射镜位移或光程差上记录干涉图来实现更高的分辨率。在光程差增大的同时,需要对所有经过干涉仪的光线保持高度的干涉仪对准一致性、光程差测量一致性和光程差一致性。
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