The Influence of Casting Static Compaction Pressure on Carbonated Reactive Magnesia Cement (CRMC)-Based Mortars

Erick Grünhäuser Soares, João Castro-Gomes, M. Magrinho
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Abstract

: The current study evaluates the influence of the static compaction pressure applied during the casting process on Carbonated Reactive Magnesia Cement-based mortars. For this purpose, mortars, embodying biomass fly ash as filler, were designed and moulded through static compaction pressures of 10, 30, 50, and 70 MPa. The moulded specimens were submitted to an accelerated carbonation curing period of 24 h under controlled conditions. The devised mortars were evaluated through compressive strength tests, and their microstructure was assessed through Mercury Intrusion Porosimetry (MIP), Thermogravimetry and Derivative Thermogravimetry (TG-DTG), and Fourier-transform Infrared Spectroscopy (FTIR) analyses. The results showed that the increment in the static compaction pressure during the specimens’ casting process not only led the mortars to reduce their porosity by up to ~30% and increase their compressive strength by up to ~58% (from 19.8 MPa to 31.2 MPa) but also that such a change seems to hinder the CO 2 diffusion into the specimens’ core, thus resulting in a lower content of carbonated products. In addition, the MIP analyses demonstrated that the static compaction pressure applied in the mortar casting process changes the pores’ characteristics, while TG-DTG and FTIR analyses provided evidence that the devised mortars were carbonated to a certain degree. Therefore, this work demonstrated that Carbonated Reactive Magnesia Cement-based mortars are highly influenced by the static compaction pressure applied during the casting process, at least up to a certain value.
铸造静压压力对碳化活性镁水泥(CRMC)基砂浆的影响
本研究评估了浇筑过程中施加的静压实压力对碳化活性镁水泥基砂浆的影响。为此,设计了以生物质粉煤灰为填料的砂浆,并在10、30、50和70 MPa的静压压力下成型。在控制条件下,将成型的试样进行24 h的加速碳化固化。通过抗压强度测试对所设计的砂浆进行了评价,并通过压汞孔隙度法(MIP)、热重法和导数热重法(TG-DTG)以及傅里叶变换红外光谱(FTIR)分析对其微观结构进行了评价。结果表明:试件浇筑过程中静压压力的增大不仅使砂浆孔隙率降低了30%,抗压强度提高了58%(从19.8 MPa提高到31.2 MPa),而且这种变化似乎阻碍了CO 2向试件芯部的扩散,从而降低了碳化产物的含量。此外,MIP分析表明砂浆浇筑过程中施加的静压压力改变了孔隙特征,TG-DTG和FTIR分析表明所设计的砂浆有一定程度的碳化。因此,这项工作表明,碳化活性镁水泥基砂浆在浇筑过程中受到静压压力的高度影响,至少达到一定值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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