Electrical behavior of PU/POMA blends

D. Kanda, J. A. Malmonge, W. F. Alves, L. F. Malmonge
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Abstract

The incorporation of conducting polymer into a conventional polymer matrix has received attention because of the possibility of combining the good processability and mechanical performance of the conventional polymer with the electrical and optical properties of conducting polymer. In this work, flexible films of polyurethane (PU) and poly(o-metoxyaniline) (POMA) blends were obtained by casting and investigated using thermally stimulated depolarisation current (TSDC) measurements. Two relaxation peaks were found in the range of -20/spl deg/C to 90/spl deg/C. The first one at T=24/spl deg/C was attributed as /spl alpha/ relaxation associated to the glass transition of PU/POMA blend and the second one located at T=60/spl deg/C can be attributed to space charge.
聚氨酯/聚甲醛共混物的电性能
将导电聚合物掺入到传统聚合物基体中,可以将传统聚合物良好的加工性能和机械性能与导电聚合物的电学和光学性能结合起来,因此受到了人们的关注。在这项工作中,通过铸造得到聚氨酯(PU)和聚邻甲氧苯胺(POMA)共混物的柔性薄膜,并使用热刺激去极化电流(TSDC)测量进行了研究。在-20 ~ 90/spl℃范围内发现两个弛豫峰。温度为24/spl度/C时的第一个变化归因于PU/POMA共混和物玻璃化转变引起的/spl α /弛豫,温度为60/spl度/C时的第二个变化归因于空间电荷。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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