Limits and Use of Polymeric Hollow Fibers as Material for Heat Transfer Surfaces

T. Kůdelová, M. Raudenský, E. Bartuli
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Abstract

Usage of plastic tubes as heat transfer surface is not a completely new issue. In 2001 a nylon car radiator was tested. Similar heat exchangers using polymeric tubes with wall thickness about 1 mm are used now in chemical industry. Low overall heat transfer coefficient of the heat exchangers with plastic tubes is cause dominantly by thick heat transfer wall and low thermal conductivity. Polymeric hollow fiber heat transfer surfaces were presented for the first time in 2004 in shell and tube heat exchanger. The paper describe progress in study of these heat transfer surfaces since that time. Typical outer diameter of fibers is in the range from 0.6 to 1.3 mm and the thickness of the wall is about 10 % of the outer diameter. Reduction of the wall thickness to about 0.1 mm reduce significantly thermal resistance. Another advantage of hollow fibers is physical fact that convective heat transfer coefficient grows with diminishing the heat transfer surfaces. Hollow polymeric fibers are made by extrusion, and production technology limits the choice of suitable polymers. Nevertheless, there are number of materials that can be extruded in small dimensions with operation temperature from 80°C to 230°C. Even if the fibers have wall thickness 0.08 mm to 0.15 mm it can withstand internal pressure of 5 to 20 MPa at room temperatures and some materials pressure of 10 MPa at temperature 120°C. Three materials of heat transfer surfaces are discussed in the paper. Polypropylene can be used for long term load by temperatures to 80°C and internal pressure of 1 MPa. This material is suitable for variety of purposes including food and chemical industry. Higher temperatures are demanded for car industry where heat exchangers should work up to 130 °C. Typical materials for medium temperature range is polyamide. Thermoplastic polymer polyether ether ketone (PEEK) can be used for extrusion of hollow fibers used for application where temperatures up to 230°C are demanded. These heat exchangers were used for flue gas condensation and for heat exchangers steam / liquid.
聚合物中空纤维作为传热表面材料的限制和使用
使用塑料管作为传热表面并不是一个全新的问题。2001年,对尼龙汽车散热器进行了测试。类似的热交换器使用的聚合物管,壁厚约1毫米,现在用于化学工业。塑料管换热器总换热系数低的主要原因是换热壁厚,导热系数低。聚合物中空纤维换热面于2004年首次应用于管壳式换热器。本文介绍了从那时起这些传热表面的研究进展。纤维的典型外径在0.6 ~ 1.3 mm之间,壁厚约为外径的10%。将壁厚降低到0.1 mm左右,热阻显著降低。中空纤维的另一个优点是它的对流换热系数随着传热面的减小而增大。中空聚合物纤维是通过挤压制成的,生产技术限制了合适聚合物的选择。然而,有许多材料可以在80°C到230°C的工作温度下以小尺寸挤压。即使纤维壁厚为0.08 mm ~ 0.15 mm,室温下也可承受5 ~ 20mpa的内压,部分材料在120℃时可承受10mpa的内压。本文讨论了三种传热表面材料。聚丙烯可在温度至80℃,内压为1mpa的条件下长期负荷使用。这种材料适用于各种用途,包括食品和化学工业。汽车工业需要更高的温度,其中热交换器应工作在130°C。中等温度范围的典型材料是聚酰胺。热塑性聚合物聚醚醚酮(PEEK)可用于挤出中空纤维,用于要求温度高达230°C的应用。这些热交换器用于烟气冷凝和蒸汽/液体热交换器。
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