Wax Deposition Pattern in Wellbore Region of Deep Condensate Gas Reservoir and Its Prevention: A Combined Experimental and Simulation Study

Zhihua Wang, Yunfei Xu, Jinling Li, Hankun Wang, Jiajun Hong, Bo Zhou, H. Pu
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Abstract

When wax deposition behavior occurs, gas condensate well suffers from moderate to serve reduction of productivity, even wellbore region blockage. For the operation and maintenance of a gas condensate well production system, a new methodology is needed to understand the wax deposition pattern in the wellbore region and assess the wax prevention under wellbore conditions. This paper establishes a phase envelope relationship in phase-behavior of typical condensate gas flow. The experiments map the potential deposition location in the wellbore region and capture the chemical wax inhibition performance in terms of wax appearance temperature (WAT), wax crystal morphology, and wax inhibiting rate, etc. The fluid component in wells for determining the envelope relationship in phase-behavior was corrected based on the gas-oil ratio of the actual gas condensate well and the carbon number distribution of the produced condensate oil-gas. The cold finger apparatus and dynamic wax inhibition measurement apparatus were designed to test wax deposition characteristics and evaluate chemical wax inhibition performance. The main test unit comprises a fully-closed high-pressure autoclave and cold finger capable of a maximum temperature of 285 °F and a maximum pressure of 16000 psi. The condensate mixtures were sampled from the wellbore region by downhole fluid sampling method. Starting from chemical wax prevention in wellbore flow, the wax crystal-improved wax inhibitor, which was mainly composed of long-chain hydrocarbons and polymers with polar groups, was employed. The temperature difference, intake pressure, stirring rate, and amount of wax inhibitor were controlled in the experiments. The wax content, WAT, and wax crystal structural characteristics of condensate systems showed noticeable differences from well to well. Using the matched component by the simulation, the wellbore temperature and pressure profiles are reliably predicted, and the envelope relationship in phase behavior of condensate gas flow is reasonably determined. Thermal and molecular diffusion are still the main mechanisms for driving wax deposition behavior in wellbore regions. The critical conditions for wax precipitation, wax deposition characteristics, and potential impact of wax deposition pattern are formulated. With the combined wellbore temperature and pressure profiles, the universal relationship schema for identifying deposition location is derived. The wax deposition location obtained from the schema agrees well with what was detected in actual production. Chemical wax prevention is an effective way to inhibit wax deposition. A maximum WAT reduction of 80% and a wax inhibiting rate of 90% could be achieved with the wax crystal improved wax inhibitor at a concentration of 0.25 wt.%. Understanding the wax deposition pattern in the wellbore region is significant for flow assurance and well operation. It provides evidence for wax prevention in wellbore flow and promotes deep condensate gas reservoir development and production efficiency.
深层凝析气藏井筒区结蜡规律及防治——实验与模拟相结合的研究
当结蜡行为发生时,凝析气井会出现中等程度的产能降低,甚至井筒区域堵塞。对于凝析气井生产系统的运行和维护,需要一种新的方法来了解井筒区域的蜡沉积模式,并评估井筒条件下的防蜡效果。本文建立了典型凝析气相行为的相包络关系。实验绘制了井眼区域的潜在沉积位置,并从蜡的外观温度(WAT)、蜡的晶体形态和蜡的抑制率等方面捕捉了化学蜡抑制性能。根据实际凝析气井的气油比和产出凝析油气的碳数分布,对用于确定相行为包络关系的井内流体组分进行了校正。设计了冷指仪和动态阻蜡仪,测试了蜡沉积特性,评价了化学阻蜡性能。主要测试单元包括一个全封闭高压高压灭菌器和冷指,最高温度为285°F,最大压力为16000 psi。通过井下流体取样法对井筒区域的凝析液混合物进行取样。从井筒流动中的化学防蜡出发,采用以长链烃和极性基团聚合物为主的蜡晶改性防蜡剂。实验控制了温差、进气压力、搅拌速率和阻蜡剂用量。不同井间凝析油体系的蜡含量、WAT和蜡晶结构特征存在显著差异。利用模拟得到的匹配分量,可靠地预测了井筒温度和压力剖面,合理地确定了凝析气流动相态的包络关系。热扩散和分子扩散仍然是驱动井筒区域蜡沉积行为的主要机制。阐述了蜡沉淀的关键条件、蜡沉积特性以及蜡沉积模式的潜在影响。结合井筒温度和压力剖面,导出了确定沉积位置的通用关系图式。从图中得到的蜡沉积位置与实际生产中检测到的情况吻合得很好。化学防蜡是抑制蜡沉积的有效途径。在0.25% wt.%的蜡晶改性阻蜡剂浓度下,WAT最大降低80%,阻蜡率达到90%。了解井筒区域的蜡沉积规律对保证流动和井作业具有重要意义。为井筒防蜡提供了依据,提高了深层凝析气藏的开发和生产效率。
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