{"title":"Partially Fluorinated Ether as an Electrolyte Additive to Modify Electrode Surface and Suppress Dissolution of Polysulfides in Li-S Batteries","authors":"Feng Qian, Jie Shao, Yu Chen, Guobin Zhu, Q. Qu, Honghe Zheng","doi":"10.1515/eetech-2018-0005","DOIUrl":null,"url":null,"abstract":"Abstract 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE), a kind of fluorinated ether, was used as an electrolyte additive for Li-S batteries. A compact, smooth, and homogenous surface layer was formed on lithium anode at the optimized amount of added TTE. In addition, TTE additive played a crucial role in modifying the composition of the passivation layer on the sulfur/carbon cathode. Consequently, the dissolution and shuttling of polysulfides were effectively prevented. The reversible capacity, initial coulombic efficiency, electrode reaction kinetic, and cycling stability of Li-S batteries were greatly improved.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"16 1 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2018-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochemical Energy Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/eetech-2018-0005","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
Abstract 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE), a kind of fluorinated ether, was used as an electrolyte additive for Li-S batteries. A compact, smooth, and homogenous surface layer was formed on lithium anode at the optimized amount of added TTE. In addition, TTE additive played a crucial role in modifying the composition of the passivation layer on the sulfur/carbon cathode. Consequently, the dissolution and shuttling of polysulfides were effectively prevented. The reversible capacity, initial coulombic efficiency, electrode reaction kinetic, and cycling stability of Li-S batteries were greatly improved.
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