Investigation on Aging Characteristics of Anti-pollution Flashover Coating under AC Voltage

Qingping Zhang, Xuefeng Li, Zhenhua Yan, Xiuguang Li, Zhipeng Shi, Yongqiang Kang
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Abstract

Room temperature vulcanized (RTV) silicone rubber coating has excellent hydrophobic performance and anti-pollution flashover characteristics, widely used in various high-voltage power equipment in China's power system. However, the insulation performance of RTV coating decreases rapidly due to aging and failure caused by long-term physical and chemical effects such as electric heating and ultraviolet. In this paper, the AC samples of RTV coating in Ningxia power grid were selected for a series of tests. The aging characteristics of RTV coatings with different years were analyzed from the aspects of sample appearance inspection, hydrophobicity, Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results showed that RTV coating of in Ningxia power grid operates well, and hydrophobicity of the coating surface is remained in HC1~ HC2 level, which meets the requirements of equipment anti-pollution performance. Through FTIR and SEM analysis, it was found that the change of peak area of characteristic functional groups on the inner and outer surfaces is related to the migration of small molecules in the RTV coating, and the cracking of main chain functional groups was the main reason for the aging of RTV coating. Moreover, small molecular substances are easy to enter and stay in the coating due to the rough surface of RTV coating and the heavy pollution characteristics in Ningxia, which increasing the hydrophobicity of the coating surface. The research results will provide a scientific basis for the aging mechanism and insulation performance evaluation of AC anti-pollution flashover coating in Ningxia power grid.
交流电压下防污闪络涂层老化特性研究
室温硫化(RTV)硅橡胶涂料具有优异的疏水性能和抗污闪络特性,广泛应用于中国电力系统的各种高压电力设备中。然而,由于长期的电加热和紫外线等物理和化学作用,RTV涂层的绝缘性能会因老化和失效而迅速下降。本文选取宁夏电网RTV涂层的交流试样进行了一系列试验。从样品外观检验、疏水性、傅里叶变换红外光谱(FTIR)和扫描电镜(SEM)等方面分析了不同年限RTV涂层的老化特性。结果表明,宁夏电网RTV涂层运行良好,涂层表面疏水性保持在HC1~ HC2水平,满足设备抗污染性能要求。通过FTIR和SEM分析发现,内外表面特征官能团峰面积的变化与RTV涂层中小分子的迁移有关,主链官能团的开裂是导致RTV涂层老化的主要原因。此外,由于RTV涂层表面粗糙,宁夏地区重污染的特点,小分子物质容易进入并停留在涂层中,增加了涂层表面的疏水性。研究结果将为宁夏电网交流抗污闪络涂层老化机理及绝缘性能评价提供科学依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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