The surface modification effect by irradiation of a surface wave excited hydrogen plasma onto zinc oxide thin films

T. Nakayama, T. Takizawa, Y. Sakamoto, K. Kashiwagi
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Abstract

[Outline] We investigate about the increase of conductivity of zinc oxide thin films by irradiating a surface wave excited hydrogen plasma. [Experiment] Zinc oxide thin films are irradiated by surface wave hydrogen plasma generated by means of microwave. The changes of the conductivity of the thin films are evaluated by using a resistivity meter. The zinc oxide thin films used here have the thickness of 1500Aring which is formed by the reactant ion plating method. Diagnosis of a film is thicknessmeter. The surface of thin films and the chemical bond state of the depth direction are measured by XRD and XPS, SIMS. The XRD and XPS, SIMS are utilized to observe the crystal and chemical structures. Transmissivity is measured by spectrophotometer. [Result] The surface resistance changes from infinite to 3.0 times 10 2[/sq], without losing transparency by irradiating hydrogen microwave surface wave plasma at a zinc oxide thin film
表面波激发氢等离子体辐照氧化锌薄膜的表面改性效果
本文研究了表面波激发氢等离子体辐照对氧化锌薄膜电导率的影响。【实验】用微波产生的表面波氢等离子体辐照氧化锌薄膜。用电阻率计测定了薄膜电导率的变化。本文采用的氧化锌薄膜厚度为1500Aring,采用反应物离子镀法形成。胶片的诊断是厚度计。采用XRD、XPS、SIMS等测量了薄膜表面深度方向的化学键态。利用XRD、XPS、SIMS等对晶体结构和化学结构进行了观察。透过率是用分光光度计测量的。[结果]氢微波表面波等离子体辐照氧化锌薄膜后,表面电阻从无限大变化到3.0 × 10 2[/sq],且不损失透明度
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