Khaoula Ferchichi, Sébastien Pecqueur, D. Guérin, R. Bourguiga, K. Lmimouni
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引用次数: 0
Abstract
Organic diode rectifier have attracted a lot of attention recently for RF energy harvesting, and much effort has been applied toward extending the ultra-high frequency range [1-2]. An important parameter that should be considered for diodes used in RF rectifier is the turn on voltage, which should be low to overcome the problem of the low voltage generated and power extracted from energy harvesting.
In this work, we focused on pentacene organic rectifier with high rectification ratio and low threshold voltage obtained by tuning the work function of gold with a self-assembled monolayer of PFBT and optimizing the thickness of the organic layer. We demonstrate a high rectification ratio up to 107 and a very low turn on voltage as low as 20 mV. Flexible rectifier diode have been also fabricated in release paper WO84, high rectification ratio of 106 was obtained even after bending of the device. The pentacene based rectifier diodes were also demonstrated to operate at more than 1GHz. This provides a great potential for fabricating high-performance organic flexible diodes and opens the way for the development of high frequency response using organic materials.
References
[1] D. Im et al, adv. Mater. 23, 644-648 (2011).
[2] C-mo. Kang et al, adv. Electron. Mater. 2, 1500282 (2016).
有机二极管整流器近年来在射频能量收集方面受到了广泛的关注,并在超高频范围的扩展方面进行了大量的研究[1-2]。射频整流器中使用的二极管应该考虑的一个重要参数是导通电压,它应该是低的,以克服从能量收集中产生的低电压和功率提取的问题。本文主要研究了利用自组装单层PFBT调节金的功函数并优化有机层厚度,从而获得具有高整流比和低阈值电压的并五苯有机整流器。我们展示了高达107的高整流比和低至20 mV的极低导通电压。在WO84脱模纸上制备了柔性整流二极管,器件弯曲后仍能获得106的高整流比。并五苯整流二极管的工作频率也超过1GHz。这为制造高性能有机柔性二极管提供了巨大的潜力,并为利用有机材料开发高频响应开辟了道路。参考文献[j] m . et al ., vol . 23, 644-648(2011)。[2] C-mo。《电子学报》。物质学报,2,1500282(2016)。