Effects of hydrophilic and hydrophobic surface modifications on poly(methyl methacrylate) denture base resins

S. Mitsuda, S. Ino, T. Nihei, Y. Umeda, Mitsuhiro Watanabe, O. Takai, H. Honma
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引用次数: 2

Abstract

Purpose: Several hydrophilic and hydrophobic approaches have been developed to prevent food debris and plaque accumulation on the denture surface. In this study, we evaluated the possibility of developing a high-functioning self-cleaning denture. Materials and Methods: Denture base resin specimens were divided into the following groups based on the type of surface treatment: control (no treatment); hydrophilic (UV irradiation or tribochemical coating); and hydrophobic (plasma chemical vapor deposition, CVD). Surface analyses were conducted using X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and atomic force microscopy. Physical strength was evaluated using the three point bending test. Data were analyzed using one-way analysis of variance followed by multiple comparisons. Results: The self-cleaning effects of the hydrophilic treatments were unsatisfactory; alternatively, the hydrophobicity, mechanical properties, and self-cleansing ability of the CVD specimens were significantly high (p < 0.05). Conclusion: Hydrophobic surface modifications effectively improved the water repelling properties of the resin without compromising its mechanical properties. (Asian Pac J Dent 2019; 19: 1-8.)
亲疏水表面改性对聚甲基丙烯酸甲酯基托树脂的影响
目的:为了防止食物残渣和牙菌斑在义齿表面堆积,研究人员开发了几种亲疏水方法。在这项研究中,我们评估了开发一种高功能自清洁义齿的可能性。材料与方法:义齿基托树脂标本根据表面处理类型分为:对照组(未处理);亲水性(紫外线照射或摩擦化学涂层);和疏水(等离子体化学气相沉积,CVD)。表面分析采用x射线光电子能谱、傅里叶变换红外能谱和原子力显微镜进行。使用三点弯曲试验评估物理强度。数据分析采用单因素方差分析和多重比较。结果:亲水性处理的自清洁效果不理想;CVD样品的疏水性、力学性能和自清洁能力均显著提高(p < 0.05)。结论:疏水表面改性在不影响树脂力学性能的前提下,有效地提高了树脂的拒水性能。(亚太杂志2019;19: 1 - 8)。
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