Review of Catalytic Transesterification Methods for Biodiesel Production

S. Nasreen, M. Nafees, L. A. Qureshi, M. Asad, A. Sadiq, Syed Danial Ali
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引用次数: 53

Abstract

Attempts for improving the synthesis procedure of catalysts for fatty acid methyl ester production have been progressing for a considerable length of time. Biodiesel lessens net carbon dioxide emissions up to 78% with reference to conventional fuel. That is the rea - son for the improvement of new and operative solid catalysts necessary for inexhaustible and efficient fuel production. Homogenous base catalysts for transesterification is risky in light of the fact that its produces soap as byproduct, which makes difficult issues like product separation and not temperate for industrial application. In comparison, hetero - geneous process gives higher quality FAME which can be effectively isolated and facili tate costly refining operations that are not required. A focus of this review article is to study and compare various biodiesel synthesis techniques that are being researched. The catalytic strength of numerous heterogeneous solid catalysts (acid and base), specially earth and transition metal oxides were also appraised. It was observed that catalytic pro ficiency relied upon a few factors, for example, specific surface area, pore size, volume and active site concentration at catalyst surface. This review article will give assistance in assortment of appropriate catalysts and the ideal conditions for biodiesel generation.
生物柴油催化酯交换技术研究进展
改进脂肪酸甲酯催化剂合成工艺的尝试已经进行了相当长的时间。与传统燃料相比,生物柴油减少了高达78%的二氧化碳净排放量。这就是改进新型和可操作的固体催化剂的原因,这是生产取之不尽用之不竭的高效燃料所必需的。均碱酯交换催化剂的副产物为肥皂,存在一定的风险,存在产品分离等难题,不适合工业应用。相比较而言,非均质工艺可以获得更高质量的FAME,可以有效地分离并简化不需要的昂贵精炼操作。本文的重点是对目前正在研究的各种生物柴油合成技术进行研究和比较。对多种非均相固体催化剂(酸和碱),特别是土和过渡金属氧化物的催化强度进行了评价。观察到催化效率取决于几个因素,如比表面积、孔径、体积和催化剂表面活性位点浓度。本文将为生物柴油生产的催化剂选择和理想条件的选择提供参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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