Light-weight High-power Lithium-ion Battery Technologies for Small SAR Satellite

Lei Gao, Yueni Mei, Guiting Yang, Honghui Gu, Ke Wang
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Abstract

Until now, the highest rate of lithium-ion battery for SAR satellite is 5 C. With the increasing requirements of light weight, related indicators can be achieved through improving rate performance and maintaining high specific energy. To meet this demand, light-weight high-power lithium-ion battery technologies for small SAR satellite have been systematically developed, including electrode active materials research, separators improvement, and electrolytes formula design. Using LiNi0.8Co0.15Al0.05O2 (NCA) materials possessing both energy and power performances as cathode materials, the design capacity of battery has been increased by 15.6% and 29%, respectively, compared with that of power lithium batteries using Li1+zNixMn1-x-yCoyO2 (NMC) and LiCoO2 (LCO) materials as cathodes. Through comparing the power performances of different types of graphite anode materials, it is found that the discharge voltage plateau under 10 C rate can be increased by 0.2 V by improving the specific capacity based on particle-size control. Besides, the effect of types of ceramic separator coating layer and separator substrates on the power performance of lithium battery has been studied. It is found that the discharge voltage plateau under 10C rate can be increased by 0.4 V and the power platform kept stable during the discharge process when dry-process polyolefin film as the substrate and Al2O3 as the ceramic coating were employed. Furthermore, for the bottleneck of poor high-temperature and cycling stability of NCA materials, the effects of several types of electrolytes on batteries’ high-rate discharge and rate cycling were compared and studied. In this study, high-power lithium-ion battery applied for small SAR satellite has been successfully prepared, exhibiting a specific capacity of 180 Wh/kg with continuous discharge capability of 10 C.
小型SAR卫星轻量化大功率锂离子电池技术
目前SAR卫星锂离子电池的最高倍率为5℃,随着对轻量化要求的不断提高,通过提高倍率性能和保持高比能来实现相关指标。为满足这一需求,小型SAR卫星轻量化大功率锂离子电池技术得到了系统的发展,包括电极活性材料研究、分离器改进、电解质配方设计等。与采用Li1+zNixMn1-x-yCoyO2 (NMC)和LiCoO2 (LCO)材料作为正极的动力锂电池相比,采用同时具有能量和功率性能的LiNi0.8Co0.15Al0.05O2 (NCA)材料作为正极的电池设计容量分别提高了15.6%和29%。通过对比不同类型石墨负极材料的功率性能,发现在粒径控制的基础上提高比容量,可将10℃速率下的放电电压平台提高0.2 V。此外,还研究了陶瓷隔膜涂层类型和隔膜衬底对锂电池功率性能的影响。结果表明,以干法聚烯烃薄膜为衬底,Al2O3为陶瓷涂层时,在10C速率下放电电压平台可提高0.4 V,放电过程中功率平台保持稳定。此外,针对NCA材料高温和循环稳定性差的瓶颈,对比研究了几种电解质对电池高倍率放电和循环倍率的影响。本研究成功制备了适用于小型SAR卫星的大功率锂离子电池,其比容量为180 Wh/kg,连续放电能力为10℃。
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