Effect of Process Temperature on Molybdenum Disulphide Layers Grown by Chemical Vapor Deposition Technique

D. Pradhan, G. Bose, S. Ghosh, N. Tripathy, J. Kar
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Abstract

Tremendous downscaling of well known semiconductor materials has resulted in various demerits like, defects at the interface and variation in bandgap. In order to overcome these challenges, the beyond graphene area of material science has been explored rapidly with the discovery of transition metal dichalcogenides (TMDC). Among TMDC, molybdenum disulphide (MoS2)has drawn tremendous attention for their excellent structural, optical, electrical and mechanical properties, which makes it suitable for the use in next generation electronic and optoelectronic devices. Initially, molybdenum (Mo)thin films were grown on silicon by RF sputtering technique at 45 W. Afterwards, sulphonation of Mo was carried out using a custom designed two zone tubular chemical vapor deposition (CVD) system. In order to optimize the growth temperature, the temperature of higher heating zone of CVD system was varied from 650 C to 850 C, The structural, morphological and optical studies reveal that the higher temperature is favorable for the growth of MoS2 layers.
工艺温度对化学气相沉积法生长二硫化钼层的影响
众所周知的半导体材料尺寸的大幅缩小导致了各种各样的缺点,如界面缺陷和带隙的变化。为了克服这些挑战,随着过渡金属二硫族化合物(TMDC)的发现,石墨烯以外的材料科学领域得到了迅速的探索。在TMDC中,二硫化钼(MoS2)因其优异的结构、光学、电学和力学性能而备受关注,适合用于下一代电子和光电子器件。首先,采用射频溅射技术在45瓦的条件下在硅上生长钼薄膜。然后,使用定制的两区管式化学气相沉积(CVD)系统进行Mo的磺化。为了优化生长温度,将CVD系统的高热区温度从650℃调整到850℃,结构、形貌和光学研究表明,较高的温度有利于MoS2层的生长。
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