Composition of catalytic layers prepared by ion beam assisted deposition of dysprosium and platinum from a pulsed arc discharge plasma onto carbon catalysts carriers

V. Poplavsky, A. Dorozhko, V. Matys
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引用次数: 0

Abstract

Plasma produced in metal vapors of a low-voltage vacuum arc discharge between two metal electrodes at their periodic contact was used to preparation surface catalytic layers by ion beam assisted deposition (IBAD) of dysprosium and platinum onto special carbon fiber catalysts carriers. Formation of layers in IBAD mode, by means of the deposition of metal and mixing of precipitating layer with the substrate by accelerated (U = 5 kV) ions of the same metal, was carried out. In this process, a neutral fraction of metal vapor and ionized plasma of vacuum pulsed electric arc were used. Investigation of the composition of prepared layers was carried out by EDX, SEM, RBS and WD-XRF methods. Electrocatalysts with the prepared layers are active in the oxidation of methanol and ethanol reactions, which are the basis of the principle of operation of low-temperature fuel cells.
用脉冲电弧放电等离子体在碳催化剂载体上离子束辅助沉积镝和铂制备催化层的组成
采用离子束辅助沉积法(IBAD)将镝和铂沉积在特殊的碳纤维催化剂载体上,制备了表面催化层。在IBAD模式下,通过金属的沉积和沉淀层与衬底的混合,以相同金属的加速离子(U = 5 kV)进行了层的形成。在这个过程中,使用了金属蒸气的中性部分和真空脉冲电弧的电离等离子体。采用EDX、SEM、RBS和WD-XRF等方法对制备层的组成进行了表征。所制备的电催化剂层在甲醇和乙醇氧化反应中具有活性,这是低温燃料电池工作原理的基础。
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