Enhancement of photocatalytic activity of TIO2 for gaseous toluene removal by simple mechanical mixing with modified zeolite

Thai Le Truong Giang, Quang Thi Hue Minh, Thai Nguyen Trieu Nguyen, Cu Hoang Minh, K. Le, Mai Hai Nghi, Le Huy Hoang, Quang Long Nguyen, Ngo Tran Hoang Duong
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Abstract

A zeolite Y was modified by the microwave-assisted method (MWA) for generating mesopores and was mechanically mixed with TiO2 for photocatalytic application. The external surface area, which is represented to the mesopore, was significantly increased about 5 to 10 times in the modified zeolites compared to the parent zeolite. The catalysts were used to catalyze the gas phase photodegradation of toluene, a volatile organic compound (VOC). The photocatalytic activity and stability of the catalyst were improved when the mesoporous zeolite was presented. The mechanical mixture contained 30 wt%. TiO2 and 70 wt%. mesoporous zeolite showed the highest toluene removal efficiency.
改性沸石对TIO2光催化去除气态甲苯活性的增强
采用微波辅助法(MWA)对Y型沸石进行改性,制备介孔,并与TiO2进行机械混合,用于光催化。改性沸石的外表面面积(以中孔为代表)比母沸石明显增加了5 ~ 10倍。用该催化剂催化了挥发性有机化合物(VOC)甲苯的气相光降解。介孔分子筛的存在提高了催化剂的光催化活性和稳定性。机械混合物含有30% wt%。TiO2和70% wt%。介孔沸石对甲苯的去除率最高。
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