Large area shunt defect free GaAs solar cells

L. Kilmer, A. Barnett
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Abstract

Shunt defects have been found to be the type of defect that can degrade and cause failure in GaAs solar cells. Because of their catastrophic effects, it is necessary to ensure that no shunt defects are formed in the solar cell. A technique for fabricating large-area shunt-defect-free GaAs solar cells has been investigated. A Be-doped GaAlAs window layer was grown directly on an n-type GaAs substrate by isothermal liquid-phase epitaxial growth (ILPE). By growing directly on the GaAs substrate and not growing the usual buffer, absorber, collector, and window layer combination, the fabrication is simplified and yields can be large. It was found that Be from the liquid GaAlAs melt diffused into the GaAs to form a complete collector layer. Because the collector is complete, a shunt-defect-free solar cell is produced. The results of the ILPE growth are reported for both 5.1 cm/sup 2/ and 0.12 cm/sup 2/ solar cells. The technique is very versatile and may be used to fabricate larger-area solar cells.<>
大面积无分流缺陷的砷化镓太阳能电池
在砷化镓太阳能电池中,分流缺陷是一种会导致电池退化和失效的缺陷。由于它们的灾难性影响,有必要确保在太阳能电池中不形成分流缺陷。研究了大面积无并联缺陷砷化镓太阳能电池的制备方法。采用等温液相外延生长(ILPE)的方法在n型GaAs衬底上直接生长出掺be的GaAlAs窗口层。通过直接在砷化镓衬底上生长,而不是生长通常的缓冲层、吸收层、集电极和窗口层组合,简化了制造过程,产量可以很大。结果表明,液态砷化镓熔体中的Be扩散到砷化镓中,形成完整的捕集层。由于集热器是完整的,因此产生了无分流缺陷的太阳能电池。报告了5.1 cm/sup /和0.12 cm/sup /太阳能电池的ILPE生长结果。这项技术用途广泛,可用于制造更大面积的太阳能电池
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