INFLUENCE OF SYNTHESIZED POWDER TITANIUM-ALUMINUM CHARGE ON MECHANICAL PROPERTIES OF EPOXYCOMPOSITES FOR SEA AND RIVER TRANSPORT

O. Sizonenko, R. Negrutsa, O. Torpakov, N. Buketova, N. Pilypchuk
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Abstract

It has been demonstrated that in order to improve anticorrosive properties and wear resistance of sea and river transport, military equipment, vehicle manufacturing, chemical, oil refining and gas industries, the utilization of polymeric epoxycomposite protective coatings is required. Polymer operational properties, including epoxy, composite materials and protective coatings based on them, have been improved due to introduction of pulverulent nano-and microdispersed fillers. ED-20 epoxy diane oligomer, PEPA polyethylene polyamine hardener and microdispersed particles synthesized by high-voltage electrical discharge powder titanium aluminum charge have been utilized to form composite materials and protective coatings used in transport industry. The relationship between the content of microdispersed powder and adhesive, stress-related properties and residual stresses of epoxy composites has been investigated. It has been proved that in order to form a composite material or protective coating with improved adhesive and cohesive properties, the desirable particle content is to be 0.05...0.50 wt.h. per 100 wt.h. of ED-20 epoxy oligomer. The advantage of the current development over foreign alternatives and those produced within the country is that it is possible to consider the main factors of corrosive environments where processing equipment is being operated, and development of materials, possessing high stress-related, heat-transfer, corrosion and wear resistance properties. Given this, an interaction-active microdispersed filler synthesized by a high-voltage electrical spark discharge has been introduced into the epoxy binder. By doing so, it is of essential importance to determine the critical content of the synthesized by high-voltage electrical discharge titanium-aluminum microdispersed powder charge during formation of protective epoxy coatings for sea and river transport.
合成粉末钛铝装药对环氧复合材料力学性能的影响
实践证明,为了提高海河运输、军事装备、车辆制造、化工、炼油和天然气工业的防腐性能和耐磨性,需要使用聚合环氧复合防护涂料。聚合物的操作性能,包括环氧树脂、复合材料和基于它们的保护涂层,由于粉状纳米和微分散填料的引入而得到了改善。利用高压放电粉末钛铝装料合成的ED-20环氧低聚物、PEPA聚乙烯多胺硬化剂和微分散颗粒,形成了用于交通运输行业的复合材料和防护涂料。研究了微分散粉末与胶粘剂含量、环氧复合材料的应力相关性能和残余应力之间的关系。实践证明,为了形成具有更好的粘结性和内聚性的复合材料或保护涂层,理想的颗粒含量为0.05 ~ 0.50 wt.h。每100 wth。ED-20环氧低聚物与国外替代品和国内生产的替代品相比,目前发展的优势在于可以考虑操作加工设备的腐蚀性环境的主要因素,以及具有高应力相关,传热,耐腐蚀和耐磨损性能的材料的发展。为此,将高压电火花放电合成的相互作用微分散填料引入到环氧粘合剂中。因此,确定高压放电合成的钛铝微分散粉料在形成海河运输环氧防护涂料过程中的临界含量具有重要意义。
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