Analysis of Wastewater Membrane Pollutants in Joint Station and Research on Biological Control Technology

Zhijian Wang, Yongqiang Pan, Dandan Yu, Chao Chen, Naifeng Zhang
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Abstract

In view of the serious membrane pollution and short stable operation period of the existing heavy oil wastewater treatment process in a combined station of an oil field, the organic pollution is determined to be the main cause of the membrane pollution on the basis of the analysis of the wastewater quality and membrane pollutants. In view of the characteristic pollutants in heavy oil wastewater, the efficient degrading bacteria were screened by restrictive culture technology, and the strains were identified as Pseudomonas and Bacillus. The effects of environmental conditions on the growth of bacteria and the degradation of heavy oil by bacteria were investigated. In the existing process, biological treatment unit was added, simulation process was established, and long-term operation experiment was carried out. The results show that after biological treatment, the oil content of wastewater is less than 1 mg/L, COD is less than 100 mg/L, suspended matter is less than 1 mg/L, and the median particle size is 0.92 um, which is better than the first kind of water injection index (SY/T 5329-2012). Biological treatment effectively degraded organic pollutants in heavy oil wastewater and delayed membrane fouling. The loss rate of membrane flux was less than 15%. The microscopic morphology of membrane surface also showed that membrane fouling was effectively suppressed.
联合站污水膜污染物分析及生物防治技术研究
针对某油田联合站现有重油废水处理工艺膜污染严重、稳定运行周期短的特点,通过对废水水质和膜污染物的分析,确定有机污染是膜污染的主要原因。针对稠油废水中污染物的特点,采用限制性培养技术筛选高效降解菌,鉴定菌株为假单胞菌和芽孢杆菌。研究了环境条件对细菌生长和细菌对稠油降解的影响。在现有工艺基础上增设生物处理单元,建立模拟工艺,并进行长期运行实验。结果表明:经生物处理后的废水含油量小于1 mg/L, COD小于100 mg/L,悬浮物小于1 mg/L,中位粒径为0.92 um,优于第一类注水指标(SY/T 5329-2012)。生物处理能有效降解稠油废水中的有机污染物,延缓膜污染。膜通量损失率小于15%。膜表面的微观形貌也表明膜污染得到了有效的抑制。
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