Study on Recycling Byproduct Salts from Waste Treatment as Disinfection Materials

Takao Hanashima, M. Soeda, Kazuo Tameda, S. Higuchi
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Abstract

CaCl 2 , NaCl, and other byproducts generated by waste treatment are landfilled as fly ash. Cl − dissolved in leachate is discharged to public water, which has an impact on agriculture and marine resources. Therefore, concentrate and dry salt (hereafter referred to as by-product salt) are generated by desalting treatment fa-cilities. This study was conducted on the possibility of recycling by-product salt as a disinfection material for wastewater treatment by generating NaClO and other compounds from it by electrolysis. As a result, a mix-ture liquid (hereafter referred to as eco hypochlorite) of NaClO and KClO with an effective chlorine concentration of above 5 , 000 mg/L was generated by a diaphragm-free electrolysis method with the concentration of salt water at 3 % and Ca 2 + at 30 mg/L. In the sterilization capacity test of eco hypochlorite, it was con-firmed that its capacity is equal to or greater than that of industrial NaClO. According to the feasibility study, when the amount of dried by-product salt is more than 0 . 5 t/day (equivalent to the amount of by-product salt generated from a city of 100 , 000 people) and recycled as disinfection material in a sewage treatment facility, it will provide economic merits to both the source (final disposal site) and the user (sewage).
垃圾处理副产物盐作为消毒材料回收利用的研究
垃圾处理产生的氯化钙、氯化钠等副产物作为飞灰填埋。Cl−溶解在渗滤液中被排放到公共水体中,对农业和海洋资源造成影响。因此,浓缩盐和干盐(以下简称副产盐)是由脱盐处理设施产生的。研究了将副产盐电解生成NaClO及其他化合物,作为废水处理消毒材料的可能性。结果表明,在盐水浓度为3%、ca2 +浓度为30 mg/L的条件下,采用无隔膜电解法制备了有效氯浓度为5000 mg/L以上的NaClO和KClO混合液(以下简称生态次氯酸盐)。在生态次氯酸盐的杀菌能力试验中,证实其杀菌能力等于或大于工业氯化钠。根据可行性研究,当副产物盐的干燥量大于0。5吨/天(相当于一个10万人口的城市产生的副产品盐的量)并在污水处理设施中作为消毒材料回收,它将为源头(最终处理场)和用户(污水)提供经济效益。
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