Peculiarities of Macro- and Microelement Accumulation in Bottom Sediments of the Crimean Coastal Water Areas (the Black Sea) with Different Water Exchange Intensity based on XRF Data

E. A. Kotelyanets
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引用次数: 1

Abstract

The paper analyzes content and spatial distribution peculiarities of macro- and microelements in the bottom sediments of Sevastopol bays, Feodosiya Gulf and Kerch Strait. Bottom sediment sampling was performed from 2005 to 2008 as well as in 2015, 2016, and 2018. Concentrations of macro- (Ti, Fe, Mn) and microelements (As, Pb, Zn, Cu, Ni, Co, Cr, V, Sr) were studied by X-ray fluorescence analysis using Spectroscan MAKS-G spectrometer. The maximal content of Cr, Co, Ni, Zn, Pb, Sr exceeding the geochemical background was found in the water areas with difficult water exchange, which include bays of the Sevastopol region under intense anthropogenic influence: the Yuzhnaya Bay, Gollandiya Bay and Kilen-Bay. In the Kazachya Bay, the least polluted in the Sevastopol bay system, the content of Cr, Co, Ni, Zn, Pb, As, Sr also exceeded their geochemical background. As illustrated by the Balaklava Bay, the paper shows the influence of local pollution sources (the Balaklavka River runoff and municipal waste water) on the microelement distribution. Sevastopol bays are characterized by high concentrations of the studied elements in the bottom sediments. In the water areas with active water exchange, i. e. Feodosiya Gulf and Kerch Strait, concentration of the studied elements, except for Ni, Zn and Cr, did not exceed on the average the geochemical background of the open Black Sea shelf areas.
基于XRF数据的克里米亚沿岸(黑海)不同换水强度下底泥宏微量元素积累特征
本文分析了塞瓦斯托波尔湾、费奥多西亚湾和刻赤海峡海底沉积物中宏量元素和微量元素的含量及其空间分布特征。2005年至2008年以及2015年、2016年和2018年进行了海底沉积物采样。利用Spectroscan MAKS-G光谱仪对宏量元素(Ti、Fe、Mn)和微量元素(As、Pb、Zn、Cu、Ni、Co、Cr、V、Sr)进行了x射线荧光分析。Cr、Co、Ni、Zn、Pb、Sr的含量最大超出地球化学背景值的水域为人类活动影响强烈的塞瓦斯托波尔地区的Yuzhnaya湾、Gollandiya湾和kilen湾。在塞瓦斯托波尔湾体系中污染最轻的Kazachya湾,Cr、Co、Ni、Zn、Pb、As、Sr的含量也超过了地球化学背景。以巴拉克拉瓦湾为例,分析了当地污染源(巴拉克拉瓦河径流和城市污水)对微量元素分布的影响。塞瓦斯托波尔海湾的特点是所研究的元素在底部沉积物中浓度很高。在Feodosiya湾和Kerch海峡等水交换活跃水域,除Ni、Zn和Cr外,所研究元素的浓度平均不超过开放的黑海陆架区的地球化学背景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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