Introduction of Polymer Nanocomposites

Teng Li, Guanglong Ding, Su‐Ting Han, Ye Zhou
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Abstract

Polymers have been one of the most important components in almost every area of human activity today. Nowadays, polymers as multifunctional materials gradually replace metals, glass, paper, and other traditional materials in various applications due to its lightweight, flexibility, and low cost [1]. In most of their applications, the applied materials are not composed of a single chemical component but mixture systems of multiple components with polymers and other additives. By incorporating different additives, such as metal, minerals, or even air, a wide variety of materials with unique physical properties and competitive production costs can be produced. For example, glass fiber-reinforced plastics are composite materials manufactured by laminating unsaturated polyester resin with glass fiber and filler, which can increase mechanical strength and heat resistance [2]. In addition, scientific research shows that the size of filling material in fiber reinforced composites has a great influence on the material properties, since the size of the filling particles largely determines the surface interactions of adhesion, particle movement, dispersion, and bonding between the surface and matrix [3]. With the particle size of the filler that gradually reduces to the nanoscale, some properties depending on the interface have undergone great changes, such as gas adsorption, chemical activity, electrical properties, and catalytic activity. Examples of different sizes of materials are shown in Figure 1.1, and a hydrogen atom is about 0.1 nm in size, while a human hair is 104 nm in diameter. Among them, nanomaterials are employed to describe the materials that have at least one dimension in the size range from approximately 1 to 100 nm [4]. Different from the bulk and microscale materials, nanomaterials are unique in that they have many unusual, useful, and interesting properties. For example, bulk gold is a very stable precious metal in golden color, which can be kept for a long time under atmospheric environment, so it is used as the initial currency by people. Unlike bulk gold, gold nanoparticles dispersed in water will show different colors according to the size of nanoparticles,
高分子纳米复合材料简介
聚合物已经成为当今人类活动几乎每个领域中最重要的组成部分之一。如今,聚合物作为多功能材料,以其轻质、柔韧性、低成本等优势,在各种应用领域逐渐取代金属、玻璃、纸张等传统材料[1]。在大多数应用中,所应用的材料不是由单一化学成分组成,而是由多种成分与聚合物和其他添加剂组成的混合物系统。通过加入不同的添加剂,如金属、矿物甚至空气,可以生产出各种具有独特物理性能和具有竞争力的生产成本的材料。例如,玻璃纤维增强塑料是由不饱和聚酯树脂与玻璃纤维和填料层合而成的复合材料,可以提高机械强度和耐热性[2]。此外,科学研究表明,纤维增强复合材料中填充材料的大小对材料性能有很大影响,因为填充颗粒的大小在很大程度上决定了表面与基体之间的粘附、颗粒运动、分散和结合等表面相互作用[3]。随着填料粒径逐渐减小到纳米级,一些依赖于界面的性能发生了很大的变化,如气体吸附、化学活性、电学性能、催化活性等。不同尺寸的材料的例子如图1.1所示,氢原子的尺寸约为0.1 nm,而人类头发的直径为104 nm。其中,纳米材料用于描述在大约1 ~ 100nm的尺寸范围内至少具有一个维度的材料[4]。纳米材料不同于体积材料和微尺度材料,其独特之处在于它具有许多不寻常的、有用的和有趣的特性。例如,散装金是一种非常稳定的金色贵金属,在大气环境下可以保存很长时间,因此被人们用作最初的货币。与大块金不同,分散在水中的金纳米粒子会根据纳米粒子的大小显示出不同的颜色,
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