Utilization of Microfluidics Technology for an Efficient Polymer Screening Process in Enhanced Oil Recovery (EOR) Applications

Safa Al Ismaili, C. Gaol, Nils Langanke, L. Ganzer
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Abstract

This work introduces an efficient approach in addition to the traditional scheme of polymer screening for the application of enhanced oil recovery. Microfluidics technology which requires less sample volumes, and less time consumption, is applied to the polymer screening procedure. This approach delivers an efficient screening process and enables the upscaling of polymer flow behavior in porous media. This work investigates three commercial polymer products, A, B, and C, which vary in average molecular weight at shear rate (0.1 – 1000 s−1) and temperature (20°C– 60°C). Fifteen polymer solutions with different concentrations are made from the three products and screened through three evaluation stages. The first stage is measuring the bulk shear viscosity of the polymer solutions in the rheometer. The second stage is conducting single-phase polymer flooding through a novel micromodel. The stage of this approach applies the results from the earlier stages by running two-phase flooding experiments that implement polymer flooding for reservoir conditions of an oil field in Oman. The micromodel structure used in this work is generated based on X-ray micro-computed tomography (μCT) images of a Bentheimer core plug. Thus, the micromodel's porosity, permeability, pore, and grain size distribution are similar to the core plug. This characteristic gives an upscaling potential to a larger scale, such as core plug or even a field implementation. A database with bulk shear viscosity and model fits (Power law & Carreau) is generated from the rheometer measurements for polymers A, B, and C. A novel 3D surface model that relates the shear rate, temperature, bulk viscosity, and concentration is developed from the data in the first stage. The single-phase flooding experiments allow the investigation of the behavior of polymer in porous media under shear and extensional flow. Furthermore, the comparison of bulk shear viscosity and in-situ viscosity shows the potential to support the analysis of an empirical constant (C-factor). In addition, polymer injectivity and retention are investigated by analyzing the pressure drop and residual resistance factor after each single-phase polymer flooding experiment. The last stage of this work provides the improvement of displacement efficiency and the recovery factor, which measures the success of the approach. The novelty of this approach is the utilization of the linear Bentheimer micromodel for delivering an efficient polymer screening process. This micromodel reflects similar rock properties as Bentheimer rocks, which provide the potential to upscale the results from microfluidics to reservoir rocks. In addition, the novel 3D surface model developed in this work allows comprehensive screening, which is accomplished through combining the parameters required in polymer evaluation at one domain.
微流控技术在提高采收率(EOR)中高效聚合物筛选中的应用
本文介绍了在传统聚合物筛分方案之外的一种提高采收率的有效方法。微流控技术应用于聚合物筛选过程中,需要较少的样品体积和较少的时间消耗。这种方法提供了一种高效的筛选过程,并使聚合物在多孔介质中的流动行为得以提升。本研究研究了三种商业聚合物产品,A, B和C,它们在剪切速率(0.1 - 1000 s−1)和温度(20°C - 60°C)下的平均分子量变化。将这三种产品制成15种不同浓度的聚合物溶液,并通过三个评价阶段进行筛选。第一阶段是在流变仪中测量聚合物溶液的整体剪切粘度。第二阶段是通过一种新的微模型进行单相聚合物驱。该方法的阶段应用了阿曼某油田油藏条件下进行的两阶段驱油实验的结果。本工作中使用的微模型结构是基于Bentheimer芯塞的x射线微计算机断层扫描(μCT)图像生成的。因此,微观模型的孔隙度、渗透率、孔隙度和粒度分布与岩心塞相似。这一特性使其具有扩大规模的潜力,例如岩心桥塞甚至现场实施。根据聚合物A、B和c的流变仪测量数据,生成了一个具有整体剪切粘度和模型拟合(Power law & Carreau)的数据库。根据第一阶段的数据,开发了一个新的3D表面模型,该模型将剪切速率、温度、整体粘度和浓度联系起来。单相驱实验可以研究聚合物在剪切和拉伸流动下在多孔介质中的行为。此外,体剪切粘度和原位粘度的比较显示了支持经验常数(c因子)分析的潜力。此外,通过分析每次单相聚合物驱实验后的压降和残余阻力系数,考察了聚合物的注入性和滞留性。最后一阶段的工作是提高驱替效率和采收率,以此来衡量该方法的成功与否。这种方法的新颖之处在于利用线性Bentheimer微模型来提供有效的聚合物筛选过程。该微观模型反映了与Bentheimer岩石相似的岩石性质,这提供了将微流体结果提升到储层岩石的潜力。此外,在这项工作中开发的新型3D表面模型允许全面筛选,这是通过在一个领域结合聚合物评估所需的参数来完成的。
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