Concentration Of Trace Metals In The Fresh And Fried Edible Vegetable Oils Used In The Production Of Plantain Chips In Ekiti State: Health Implications

E. Adeyeye, R. Akinyeye, A. J. Adesina
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Abstract

Seven selected heavy metals namely Fe, Cu, Mn, Pb, Zn, Cd and Ni in five vegetable oils used in frying plantains (fresh and fried) collected from Ado-Ekiti, Ekiti State, were determined by graphite furnace atomic absorption spectrometry (GF-AAS) after microwave digestion. The accuracy of procedure was confirmed by certified reference materials (NIST). The relative standard deviations were found below 10%. In all the various oils (fresh and processed), the concentrations for Fe, Cu, Mn, Pb, Zn, Cd and Ni were observed in the range of 0.0005 -0.0018, 0.0002 – 0.0009, 0.0004 – 0.0021, 0.0001- 0.0007, 0.0003 – 0.0016, 0.0001 – 0.006 and 0.0002-0.0010 mg/kg, respectively. In general, among all the oils, fresh palm oil (FPO had the highest concentration) for all the selected heavy metals. Comparing with safety intake levels for these heavy metals recommended by Institute of Medicine of the National Academies (IOM), US Environmental Protection Agency (USEPA) and Joint FAO/WHO Expert Committee on Food Additives (JECFA), the dietary intakes of the seven heavy metals from daily consumption of edible vegetable oils for a 70 kg (adult) and 24 kg (children) body weight should pose no significant health risk to consumers. However, for adults and children, the THQ and HI were low. The TCR values also indicate low to moderate carcinogenic risks for adults and children.
埃基蒂州大蕉片生产中使用的新鲜和油炸食用植物油中微量金属的浓度:健康影响
采用微波消解石墨炉原子吸收光谱法(GF-AAS)对采自埃基蒂州阿多-埃基蒂州的5种煎炸大蕉(新鲜和煎炸大蕉)植物油中的Fe、Cu、Mn、Pb、Zn、Cd和Ni 7种重金属进行了测定。通过标准物质(NIST)验证了该方法的准确性。相对标准偏差均小于10%。在各种油(新鲜和加工)中,Fe、Cu、Mn、Pb、Zn、Cd和Ni的浓度分别为0.0005 ~ 0.0018、0.0002 ~ 0.0009、0.0004 ~ 0.0021、0.0001 ~ 0.0007、0.0003 ~ 0.0016、0.0001 ~ 0.006和0.0002 ~ 0.0010 mg/kg。总的来说,在所有油中,新鲜棕榈油(FPO)对所有选定的重金属浓度最高。与美国国家科学院医学研究所(IOM)、美国环境保护署(USEPA)和粮农组织/世卫组织食品添加剂联合专家委员会(JECFA)建议的这些重金属安全摄入量相比,70公斤(成人)和24公斤(儿童)体重每日食用植物油中摄入的七种重金属应不会对消费者造成重大健康风险。然而,成人和儿童的THQ和HI都很低。TCR值也表明对成人和儿童有低至中等的致癌风险。
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