Fe3O4@[email protected]: A Magnetic Metal–Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides

IF 3.784 3区化学 Q1 Chemistry

ACS Combinatorial Science Pub Date : 2020-11-13 DOI:10.1021/acscombsci.0c00178

Arash Ghorbani-Choghamarani*, Zahra Taherinia*

引用次数: 10

Abstract

A novel magnetic metal–organic framework (Fe₃O₄@[email?protected]) has been prepared and characterized by spectroscopic, microscopic, and magnetic techniques. This magnetically separable catalyst exhibited high catalytic activity for nitrile hydration and the ability to reduce isothiocyanates, isocyanates, and isocyanides with excellent activity and selectivity without any additional reducing agent.

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Fe3O4@[email protected]:一种磁性金属-有机骨架作为可回收催化剂用于硝基水化和还原异硫氰酸酯、异氰酸酯和异氰酸酯

制备了一种新型磁性金属有机骨架(Fe3O4@[email?protected])，并通过光谱、微观和磁性技术对其进行了表征。该磁性可分离催化剂对丁腈水化具有较高的催化活性，并具有还原异硫氰酸酯、异氰酸酯和异氰酸酯的能力，具有优异的活性和选择性，无需任何额外的还原剂。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ACS Combinatorial Science CHEMISTRY, APPLIED-CHEMISTRY, MEDICINAL

自引率

0.00%

发文量

审稿时长

1 months

期刊介绍： The Journal of Combinatorial Chemistry has been relaunched as ACS Combinatorial Science under the leadership of new Editor-in-Chief M.G. Finn of The Scripps Research Institute. The journal features an expanded scope and will build upon the legacy of the Journal of Combinatorial Chemistry, a highly cited leader in the field.