{"title":"Pyrite contact twins.","authors":"Yves Moëlo, Massimo Nespolo, François Farges","doi":"10.1107/S2052520622011714","DOIUrl":null,"url":null,"abstract":"<p><p>Two examples of contact twins in pyrite from Peru are described. The first one, from Pasto Bueno ore deposit, shows the pyritohedron {120} as principal form, accompanied by the {111} octahedron and {100} cube as secondary forms, giving a lenticular aspect. (111) is the composition plane, and the twin operation is any one of the three binary axes ⟨110⟩ within this plane. The second one (unknown ore deposit) presents two forms, the octahedron {111} and the pyritohedron {120}; the two crystals in the twin are elongated along [101] and [011], respectively, producing a V profile. It is a reflection twin where the twin plane (110) coincides with the composition plane. These twins are by merohedry. Another contact twin is known in the literature, reported by Gaubert [Bull. Soc. Fr. Minéral. Cristallogr. (1928), 51, 211-212] who described it as a spinel twin, i.e. a reflection twin with twin and composition plane (111); here it is shown that it is actually a rotation twin in which the twin operation is a 180° rotation about any of the three equivalent directions ⟨211⟩, contained in the (111) composition plane. The occurrence of these twins as well as the doubtfulness of the spinel twin in pyrite shows a direct relationship with the structural interpretation based on the pseudo-symmetry of the crystallographic orbits.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1107/S2052520622011714","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1
Abstract
Two examples of contact twins in pyrite from Peru are described. The first one, from Pasto Bueno ore deposit, shows the pyritohedron {120} as principal form, accompanied by the {111} octahedron and {100} cube as secondary forms, giving a lenticular aspect. (111) is the composition plane, and the twin operation is any one of the three binary axes ⟨110⟩ within this plane. The second one (unknown ore deposit) presents two forms, the octahedron {111} and the pyritohedron {120}; the two crystals in the twin are elongated along [101] and [011], respectively, producing a V profile. It is a reflection twin where the twin plane (110) coincides with the composition plane. These twins are by merohedry. Another contact twin is known in the literature, reported by Gaubert [Bull. Soc. Fr. Minéral. Cristallogr. (1928), 51, 211-212] who described it as a spinel twin, i.e. a reflection twin with twin and composition plane (111); here it is shown that it is actually a rotation twin in which the twin operation is a 180° rotation about any of the three equivalent directions ⟨211⟩, contained in the (111) composition plane. The occurrence of these twins as well as the doubtfulness of the spinel twin in pyrite shows a direct relationship with the structural interpretation based on the pseudo-symmetry of the crystallographic orbits.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.