Hemilability and structural considerations in complexes of platinum(II) comprising bis(diphenylphosphanyl)methane monoxide, monosulfide, and monoselenide.

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Acta Crystallographica Section C Structural Chemistry Pub Date : 2023-09-01 DOI:10.1107/S2053229623007325

Jack Faller, Jonathan Parr

引用次数: 0

Abstract

The structure of a platinum(II) complex containing (R)-(dimethylamino)ethylnapthyl and bis(diphenylphosphanyl)methane monosulfide ligands, namely, {(R)-1-[1-(dimethylamino)ethyl]napthyl-κ²N,C²}[(diphenylphosphanylmethyl)diphenylphosphine sulfide-κ²P,S]platinum(II) hexafluoridoantimonate dichloromethane monosolvate, [Pt(C₁₄H₁₆N)(C₂₅H₂₂P₂S)][SbF₆]·CH₂Cl₂, was determined. The structural features are compared with analogous platinum bis(diphenylphosphanyl)methane monoxide [dppm(O)] and bis(diphenylphosphanyl)methane monoselenide [dppm(Se)] complexes in relation to their potential hemilability and stereochemical nonrigidity.

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含二(二苯基磷酰)甲烷一氧化碳、单硫化物和单硒化物的铂(II)配合物的半半性和结构考虑。

测定了含(R)-(二甲氨基)乙基萘酰基和双(二苯基磷酰)甲烷单硫配体的铂(II)配合物{(R)-1-[1-(二甲氨基)乙基]萘酰基-κ 2n,C2}[(二苯基磷酰甲基)二苯基磷硫醚-κ 2p,S]铂(II)六氟锑酸二氯甲烷单溶剂化物[Pt(C14H16N)(C25H22P2S)][SbF6]·CH2Cl2的结构。与类似的铂-二(二苯基磷酰)甲烷一化物[dppm(O)]和二(二苯基磷酰)甲烷单硒化物[dppm(Se)]配合物的结构特征进行了比较，比较了它们潜在的半半性和立体非刚性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Acta Crystallographica Section C Structural Chemistry CHEMISTRY, MULTIDISCIPLINARYCRYSTALLOGRAPH-CRYSTALLOGRAPHY

CiteScore

1.60

自引率

12.50%

发文量

148

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.