Evidence for Borylene Carbonyl (LHB═C═O) and Base-Stabilized (LHB═O) and Base-Free Oxoborane (RB≡O) Intermediates in the Reactions of Diborenes with CO2

已完结 10 由 dddd 发布于 2026/10/10 18:19:22

DOI:10.1021/jacs.2c00479
作者：Andreas Stoy,?Marcel H?rterich,?Rian D. Dewhurst,?J. Oscar C. Jiménez-Halla,?Peter Endres,?Maximilian Ey?elein,?Thomas Kupfer,?Andrea Deissenberger,?Torsten Thiess,?Holger Braunschweig*
文献类型：期刊论文
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American Chemical Society (ACS)

Abstract：Doubly N-heterocyclic-carbene-stabilized diborenes undergo facile reactions with CO2, initially providing dibora-β-lactones. These lactones convert over time to their 2,4-diboraoxetan-3-one

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