Caging the Chlorine Radical: Chemoselective Photocatalytic C(sp3)–H Functionalization Enabled by Terminal Cu–Cl Sites in a Metal–Organic Framework

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DOI:10.1021/jacs.5c18222
作者：Mary C. Eaton,?, ,?Akash K. Ball,?, ,?Katrina E. Doherty,?, ,?Sky Chen,?, ,?Daniel T. Nakamura,?, ,?Tyler J. Azbell,?, ,?Heather J. Kulik,?, and ,?Phillip J. Milner*,?
文献类型：期刊论文
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American Chemical Society (ACS)

Abstract：Hydrogen atom transfer (HAT) mediated by halogen radicals represents a powerful approach for the functionalization of inert C(sp3)–H bonds. Chlorine radical (Cl•), for example, is capable of

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