Interception of Transient Allyl Radicals with Low-Valent Allylpalladium Chemistry: Tandem Pd(0/II/I)–Pd(0/II/I/II) Cycles in Photoredox/Pd Dual-Catalytic Enantioselective C(sp3)–C(sp3) Homocoupling

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DOI:10.1021/jacs.4c00676
作者：Bo Li,?Hong-Hao Zhang,?Yongrui Luo,?Shouyun Yu*,?William A. Goddard III* and Yanfeng Dang*,?
文献类型：期刊论文
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American Chemical Society (ACS)

Abstract：We present comprehensive computational and experimental studies on the mechanism of an asymmetric photoredox/Pd dual-catalytic reductive C(sp3)–C(sp3) homocoupling of allylic electrophiles.

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