Direct Reduction of NO to N2O by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO}7 Complex

已完结 10 由 Gs 发布于 2026/8/31 10:20:41

DOI:10.1021/acs.inorgchem.2c02383
作者：Aniruddha Dey, Therese Albert, Richard Y. Kong, Samantha N. MacMillan, Pierre Mo?nne-Loccoz*, Kyle M. Lancaster* and David P. Goldberg*, 
文献类型：期刊论文
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American Chemical Society (ACS)

Abstract：Addition of NO to a nonheme dithiolate-ligated iron(II) complex, FeII(Me3TACN)(S2SiMe2) (1), results in the generation of N2O. Low-temperature spectroscopic studies reveal a metastable six-c

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