Br?nsted Acid-Lewis Acid (BA-LA) Induced Final Deprotection/Peptide Resin Cleavage in Fmoc/t-Bu Solid-Phase Peptide Synthesis: HCl/FeCl₃ and AcOH/FeCl₃ as Viable PFAS-Free Alternatives for TFA.

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DOI:10.1021/acs.orglett.4c02569
作者：Jan Pawlas,?Christophe André,?Jon H Rasmussen,?Olivier Ludemann-Hombourger
文献类型：期刊论文
补充材料：只需要正文

American Chemical Society (ACS)

Abstract：The widely used Fmoc/t-Bu solid-phase peptide synthesis (SPPS) is hampered by relying on corrosive, per/polyfluoroalkyl substance (PFAS) classified trifluoroacetic acid (TFA) as a universal

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Br?nsted Acid-Lewis Acid (BA-LA) Induced Final Deprotection/Peptide Resin Cleavage in Fmoc/t-Bu Solid-Phase Peptide Synthesis: HCl/FeCl3 and AcOH/FeCl3 as Viable PFAS-Free Alternatives for TFA.

Br?nsted Acid-Lewis Acid (BA-LA) Induced Final Deprotection/Peptide Resin Cleavage in Fmoc/t-Bu Solid-Phase Peptide Synthesis: HCl/FeCl₃ and AcOH/FeCl₃ as Viable PFAS-Free Alternatives for TFA.